Nearest neighbor effect on the isomer shift of 57Fe in small metal clusters

Dyson, William; Montano, P. A.

doi:10.1016/0038-1098(80)90351-8

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1983

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Cited by 29 publications

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“…Alternatively, a distribution of small particles could also lead to a spectrum of isomer shifts. 26 It is not possible to distinguish between these two possibilities at present.…”

Section: Discussionmentioning

confidence: 99%

Iron-57 Moessbauer spectroscopy of reduced cathodes in the lithium/iron disulfide battery system: evidence for superparamagnetism

Jones¹,

Kovacs²,

Sharma³

et al. 1990

J. Phys. Chem.

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“…Alternatively, a distribution of small particles could also lead to a spectrum of isomer shifts. 26 It is not possible to distinguish between these two possibilities at present.…”

Section: Discussionmentioning

confidence: 99%

Iron-57 Moessbauer spectroscopy of reduced cathodes in the lithium/iron disulfide battery system: evidence for superparamagnetism

Jones¹,

Kovacs²,

Sharma³

et al. 1990

J. Phys. Chem.

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Ligandenfreie Metallcluster

Ozin

Mitchell

1983

Angewandte Chemie

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Ligand‐Free Metal Clusters

Ozin

Mitchell

1983

Angew. Chem. Int. Ed. Engl.

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Recent advances in the synthesis and spectroscopic characterization of ligand-free metal clusters immobilized in cryogenic rare gas matrices have contributed greatly to the understanding of electronic, geometric, dynamic, and chemical bonding properties of a wide range of uni-and bimetallic clusters as a function of nuclearity and metal type. The knowledge accumulated on molecular metal aggregates devoid of ligands and isolated on various supports will form an important data base for gauging the reliability of quantum chemical calculations on metal clusters, as well as for comprehending certain aspects of chemisorption on, and catalysis by, supported metal clusters. It can be envisaged that information on ligand-free metal clusters entrapped in a wide range of matrix environments in conjunction with the data for these same metal clusters in the gas phase and in molecular beams will probably contribute towards understanding metal-support interactions and to the designed synthesis of a new breed of high-technology heterogeneous catalysts in the not too distant future.

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Nearest neighbor effect on the isomer shift of 57Fe in small metal clusters

Cited by 29 publications

References 9 publications

Iron-57 Moessbauer spectroscopy of reduced cathodes in the lithium/iron disulfide battery system: evidence for superparamagnetism

Iron-57 Moessbauer spectroscopy of reduced cathodes in the lithium/iron disulfide battery system: evidence for superparamagnetism

Ligandenfreie Metallcluster

Ligand‐Free Metal Clusters

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