Facile syntheses
of branched hematite (α-Fe2O3) crystals
with fine-tuning of their nanoscale subunit morphologies
were reported. Starting from Prussian red and bisolvent systems with
controlled temperature as the crucial parameters, fine-tuning of the
nanoscale subunit morphologies in the context of controlling the anisotropic
growth of branched α-Fe2O3 crystals was
demonstrated. The systematic and optimized studies significantly improved
the controlled synthesis of the hierarchical growth of nanoscale subunits,
leading to the formation of branched dendritic leaflike (secD3D, tertD2D, and tertD3D) and
hyperbranched (secS2D and hypB2D)
α-Fe2O3 particles for their size-reduced
variants used in photocatalysis. The kinetics of the photo-Fenton
degradation of three azo dyes (chlorazol black, direct blue, and methyl
orange) with five types of branched dendritic α-Fe2O3 particles were compared systematically.