2019
DOI: 10.1038/s41598-019-55310-8
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Near ideal synaptic functionalities in Li ion synaptic transistor using Li3POxSex electrolyte with high ionic conductivity

Abstract: All solid-state lithium-ion transistors are considered as promising synaptic devices for building artificial neural networks for neuromorphic computing. However, the slow ionic conduction in existing electrolytes hinders the performance of lithium-ion-based synaptic transistors. In this study, we systematically explore the influence of ionic conductivity of electrolytes on the synaptic performance of ionic transistors. Isovalent chalcogenide substitution such as Se in Li3PO4 significantly reduces the activatio… Show more

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Cited by 72 publications
(95 citation statements)
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“…However, electrochemical transistors have suffered from small dynamic range and short retention issues. An electrochemical transistor composed of a Se-doped lithium phosphate (Li 3 PO x Se x ) electrolyte with a high ionic conductivity was proposed as an artificial synapse ( Figure 5 A) ( Nikam et al., 2019 ). For comparison, an electrochemical transistor was also fabricated using lithium phosphate (Li 3 PO 4 ) as an electrolyte that had lower ionic conductivity compared with Li 3 PO x Se x .…”
Section: Artificial Synapses Based On Emerging Materialsmentioning
confidence: 99%
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“…However, electrochemical transistors have suffered from small dynamic range and short retention issues. An electrochemical transistor composed of a Se-doped lithium phosphate (Li 3 PO x Se x ) electrolyte with a high ionic conductivity was proposed as an artificial synapse ( Figure 5 A) ( Nikam et al., 2019 ). For comparison, an electrochemical transistor was also fabricated using lithium phosphate (Li 3 PO 4 ) as an electrolyte that had lower ionic conductivity compared with Li 3 PO x Se x .…”
Section: Artificial Synapses Based On Emerging Materialsmentioning
confidence: 99%
“… (D) Potentiation/depression of Li 3 PO x Se x -based electrochemical transistor using 90 identical pulses (±1.5 V, 1 s). Reproduced with permission ( Nikam et al, 2019 ). Copyright 2019, Springer Nature.…”
Section: Artificial Synapses Based On Emerging Materialsmentioning
confidence: 99%
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“…Refs. [30], [80] and [82] use the same calculation method, while ref. [21] and this work use the same calculation method.…”
mentioning
confidence: 99%
“…They show evidence that alloy nanoparticles-based devices have reproducible diffusive switching characteristics and offer a high design versatility to tune such switching properties. The form of the resistance state is crucial for the successful training of artificial neural networks; Nikam et al 6 present a Li ion synaptic transistor with high ionic conductivity that allows linear conductance switching with several discrete non-volatile states. Also in 7 the impact of Li-based devices for the emulation of synaptic behaviour is shown.…”
mentioning
confidence: 99%