1991
DOI: 10.1063/1.106003
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Nd3+ incorporation in CaF2 layers grown by molecular beam epitaxy

Abstract: Molecular beam epitaxy of Nd3+-doped CaF2 monocrystalline layers on CaF2 substrates is demonstrated. Nd concentration is controlled by the temperature of an evaporation cell containing NdF3. Photoluminescence spectra of the samples show emissions from Nd3+ centers in tetragonal symmetry sites as a consequence of the charge compensation mechanism provided by interstitial F− ions.

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Cited by 27 publications
(9 citation statements)
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“…5 CaF 2 :Nd 3ϩ thin films grown by MBE on CaF 2 substrates have been extensively studied. [6][7][8] Trivalent Nd 3ϩ ions enter in divalent Ca 2ϩ sites. A charge compensation mechanism is needed to ensure the global electrical neutrality of the crystal.…”
Section: Introductionmentioning
confidence: 99%
“…5 CaF 2 :Nd 3ϩ thin films grown by MBE on CaF 2 substrates have been extensively studied. [6][7][8] Trivalent Nd 3ϩ ions enter in divalent Ca 2ϩ sites. A charge compensation mechanism is needed to ensure the global electrical neutrality of the crystal.…”
Section: Introductionmentioning
confidence: 99%
“…Although there are reports in the literature on MBE growth of waveguide films of complex ternary oxide materials such as LiNbO 3 [120] and BaTiO 3 [121], most of the work on dielectric waveguide layers to date has focused on hetero-epitaxial deposition of rare-earth doped fluoride waveguides, such as ZnF 2 , PbF 2 , [122] CaF 2 , [123] and LaF 3 [124][125][126][127]. They were grown on different dielectric and semiconductor substrates and their propagation loss was on the order of 1 dB·cm -1 [122,126,127].…”
Section: Molecular Beam Epitaxy (Mbe)mentioning
confidence: 99%
“…In particular, Nd 3ϩ and Er 3ϩ doped CaF 2 layers have been grown on CaF 2 , GaAs, or Si substrates, [5][6][7] and recently the growth of ZnF 2 and PbF 2 -SrF 2 layers on MgF 2 and GaAs substrates, respectively, has been reported. 8 The possibility of growing good quality homoepitaxial CaF 2 layers incorporating very high concentrations of Er 3ϩ ions, up to 50 mol %, 9 has opened interesting prospects for amplification or laser action.…”
Section: Introductionmentioning
confidence: 99%