NbCl₅ Promoted the Efficient Synthesis of Phthalein Derivatives: Optical Characterization and Solvatochromic Effect

Abstract

Organic dyes derived from phthaleins have a large number of industrial applications and can be synthesized using a Lewis acid by Friedel–Crafts acylation, followed by an addition reaction to the carbonyl compound. This work aims to investigate the use of NbCl5 as a catalyst for the acylation reaction. The behavior of the phthalein derivatives in several solvents and when subjected to different pH conditions was studied. These compounds showed a color‐changing effect depending on the pH and solvent, making them useful for applications as indicators. The phthaleins change their conformations depending on the condition of the medium. Photophysical studies of these compounds were carried out through their UV–Vis absorption spectra. Here, we show the umbrella‐like conformation change of phthalein derivatives that depend on the solvent and the pH of the medium.

Hexaniobate as a Recyclable Solid Base Catalyst to Activate C–H Bonds in Lignin Linkage Boosting the Production of Aromatic Monomers

“…Meanwhile, a new UV absorption peak at 550–600 nm attributed to the deprotonation of phenolphthalein in basic medium was observed (Figure S10). Notably, the slightly higher peak intensity of KNb 6 reveals that solid base KNb 6 has a better deprotonation ability than homogeneous KOH (Figure b).…”