Natural cocrystallisation of two ferrocenyl compounds

Naskar, Jnan Prakash; Chowdhury, Shubhamoy; Drew, Michael G. B.; Datta, Dipankar

doi:10.1039/b408917k

Cited by 4 publications

(3 citation statements)

References 17 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Compound 4 b was synthesized as follows [23] . Ferrocene formaldehyde azine 4 c and compound 5 were also synthesized by the same method [24,25] . Add compound 2 (99.023 mg, 0.250 mmol), o ‐hydroxybenzaldehyde (61.060 mg, 0.500 mmol), triphenylphosphorus (131.150 mg, 0.500 mmol), t ‐BuOLi (22.014 mg, 0.275 mmol), and 5 mL of dry dioxane into a 25 mL Schlenk flask.…”

Section: Methodsmentioning

confidence: 99%

See 1 more Smart Citation

Synthesis, Anti‐migration and Catalytic Effect of Ferrocene Azine Derivatives on the Thermal Decomposition of Ammonia Perchlorate

Guo

Huo

Zhao

et al. 2022

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

Ferrocene burning rate catalyst (BRC) is a common catalyst to promote the combustion of composite solid propellant because of its high catalytic performance, but this kind of catalyst has the disadvantage of easy migration. Ammonia perchlorate (AP) is the main oxidant of composite solid propellant, and its thermal degradation behavior has an important impact on the combustion of propellant. New mononuclear and polynuclear ferroceneazine BRCs were synthesized, and their structures were characterized by UV-Vis, NMR, HRMS and IR spectra. The catalytic effects of these ferrocenylazines on the thermal degradation of AP were studied by DSC and TG. The results confirmed that the catalytic performance of azine without bisferrocenylpropane was inferior to that of Catocene (Cat), while the catalytic performance of azine with bisferrocenylpropane was equivalent to that of Cat. Anti-migration studies showed that both mononuclear ferroceneazines and Cat showed mobility, while polynuclear ferroceneazines did not migrate after long-term storage. Therefore, polynuclear ferroceneazine is a new kind of high-efficiency and non-migration BRC with application prospects.

show abstract

Section: Methodsmentioning

confidence: 99%

“…[23] Ferrocene formaldehyde azine 4 c and compound 5 were also synthesized by the same method. [24,25] Add compound…”

Section: Synthesis Of 4 Andmentioning

confidence: 99%

Synthesis, Anti‐migration and Catalytic Effect of Ferrocene Azine Derivatives on the Thermal Decomposition of Ammonia Perchlorate

Guo

Huo

Zhao

et al. 2022

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

show abstract

“…Ferrocenyl groups in some molecules adopt the high energy eclipsed configuration upon cocrystallisation [4]. Even the property of the conglomerate may be different from those of the constituent molecules.…”

Section: Graphical Abstract 1 Introductionmentioning

confidence: 99%