The Rapid Communications section is intended for the accelerated publication of important new results Sin.ce manuscripts submitted to this section are given priority treatment both in the editorial once and in production, authors should explain in their submittal letter why the work justifies this special handling A.Rapid Communication should be no longer than 3/'~printed pages and must be accompanied by an abstract. Page proofs are sent to authors Absolute ionization energy of the 2 'S level of helium %e have measured the absolute wave numbers of a series of transitions from the metastable 2'S level of helium to the n P (n 7-74) excited states. From these data we determine the binding energy of the 2 'S level to 2.2 parts in 10' by using a Ritz series formula. This high-precision determination of the 2 'S binding energy does not depend on theoretical calculation of the binding energy of any helium level. The result, 32033.228855(7) cm ', confirms our earlier finding of a relatively large discrepancy with the predicted two-electron Lamb shift for the 2 'S level.PACS number(s): 35. IO. Hn, 32.30.Jc, 12.20.Fv In a recent paper [I], we reported an experimental determination of the binding energy of the first excited singlet state of helium (2'5) that deviated significantly from the best available QED predictions. This result was subsequently confirmed to higher precision by Lichten, Shiner, and Zhou [2). Although these two experiments observed transitions to difl'erent levels and used difl'erent metrological techniques, both relied upon the calculated energies of selected high-lying levels to tie experimentally measured transition energies to the ionization limit. It is assumed that these high-lying levels, for which QED corrections to the energy are small, can be calculated with very high accuracy. This approach to determining the 2 S binding energy, while reasonable, remains somewhat unsatisfying since it is not entirely independent of theory.Clearly, any error that may exist in the calculated binding energy of the high-lying levels enters directly into the reported value for the 2 'S level.In the present work we exploit the predictable behavior of an unperturbed Rydberg series of levels to determine the 2 'S ionization energy. We assume only the general form of the distribution of energy levels and do not require the results of any precise theoretical calculation. In this paper we will describe this approach, briefly discuss our experiment, and present our result for the 2 'S ionization energy. A more detailed report will be given in 'a subsequent publication.It has long been known on an empirical basis that an unperturbed series of energy levels can be represented by the extended Ritz formula E"=E -R/(nb") where E" is the energy of the level with principal quantum number n, E is the ionization energy, R is the finite-mass Rydberg constant for the species of interest, and 8" is the quantum defect given by S"-A+8/(n 8") '+c/(n a-)'+-This formula has been derived from general quantummechanical considerations by ...