NASICON-type Li&lt;sub&gt;1.5&lt;/sub&gt;Al&lt;sub&gt;0.5&lt;/sub&gt;Ge&lt;sub&gt;1.5&lt;/sub&gt;(PO&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt; Containing Amorphous Phase for Solid Li-Ion Conductor

KAWANO, Yoichiro; KATO, Akihiko; USUI, Hiroyuki; DOMI, Yasuhiro; SAKAGUCHI, Hiroki

doi:10.5796/electrochemistry.23-00088

Cited by 1 publication

(2 citation statements)

References 13 publications

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“…2,19 Similarly, we already confirmed that GeO 2 is formed at higher sintering temperatures of amorphous LAGP. 20 It was attributed to the presence of amorphous GeO 2 in the amorphous LAGP. Amorphous LAGP is obtained by melting the raw materials of LAGP at 1300 °C and quenching the melt assuming that a small amount of Li volatilizes during the sintering process.…”

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confidence: 99%

“…We have already reported the results of our investigation into the redox behavior of LAGP sintered at 600 °C. 20 The calculations of the electronic density of states for the constituent elements of LAGP using first-principles calculations indicates significant influences on Ge and O at the lowest position of the conduction band on the reduction side. A reduction of GeO is expected, and some reduction of P is also implied.…”

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Electrochemical Anode Behavior of α-FeSi<sub>2</sub> Co-Sintered with Solid Electrolyte

KAWANO,

KATO,

DOMI

et al. 2024

Electrochemistry

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It is essential in the production of the next generation of rechargeable batteries to elucidate the reaction phases formed after co-sintering in allsolid-state batteries with oxide solid electrolytes and silicon materials and their electrochemical behavior. Herein, we explore the presence or absence of reaction phases and the charge/discharge behavior after co-sintering with the solid electrolyte Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 (LAGP) and various silicon active anode materials. In the co-sintering investigation of LAGP and silicon active anode materials, α-FeSi 2 do not react with LAGP and the electronic conductivity of α-FeSi 2 is maintained even after sintering. In addition, using a mixed sintered sheet consisting of α-FeSi 2 , solid electrolyte LAGP, and carbon additive vapor-grown carbon fiber, a charge/discharge test is performed at 105 °C for the cell with a Li metal counter electrode and polymer electrolyte. The results of X-ray diffraction measurements of the disassembled test cell after charging/discharging confirm that the reduction decomposition reaction proceeding and disappearing of LAGP phase completely when Li is inserted into the active anode material for the first time. However, when Li is further inserted, Li alloy phases, Li 22 Si 5 , and Li 22 Ge 5 appear, and they show reversible charge/discharge behavior of 400 mA h g −1 . This is presumed to be owing to the partial reduction of α-FeSi 2 to Si and the reduction decomposition of LAGP to produce Ge during the Li insertion process, followed by the formation of Li alloy phases with Li and Si or Ge. Furthermore, while the solid electrolyte LAGP disappear during the first Li insertion, the formation of a Li 4 SiO 4 phase with a broad peak is observed, suggesting that the Li 4 SiO 4 phase might function as a Li conductor.

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Section: Resultsmentioning

confidence: 99%

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confidence: 99%