Abstract:The vibrational levels of O2(X3Sigma(g)-) generated in the ultraviolet photolysis of O3 at 266 nm were detected via laser-induced fluorescence (LIF) of the B3Sigma(u)- - X3Sigma(g)- system. The nascent vibrational energy distributions of O2(X3Sigma(g)-, nu = 6-13) have been measured by two different methods. One is a kinetic analysis based on the originally developed integrated profiles method (IPM). The time-resolved LIF of a single vibrational level has been recorded in the presence of CF4 or O2 as a relaxat… Show more
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