This paper presents the design and development of a passive wireless sensor for the detection of bio-hazard materials and vapors using chemiresistive thin films. Composite polymer thin film with functionalized carbon nanotubes (f-CNT) and polymethylmethacrylate (PMMA) is employed as a sensing material. It is investigated that resistance change is determined with the concentration of dichloromethane vapors diffused into composite thin film, due to electrical transition from direct contact to tunneling in carbon nanotube nanojunctions. The chemiresistive film is integrated into a passive wireless system which works based on the change in phase of the reflected RF signal. Measurement results of sensors in a wireless sensing system show a large differential phase shift, which can be utilized for remote monitoring of bio-hazard vapors in real time.