We report the first optical parametric generator (OPG) based on the new nonlinear material, orientationpatterned gallium phosphide (OP-GaP). Pumped by a Qswitched nanosecond Nd:YAG laser at 1064 nm with 25 kHz pulse repetition rate, the OPG can be tuned across 1721-1850 nm in the signal and 2504-2787 nm in the idler. Using a 40-mm-long crystal in single pass, we have generated a total average output power of up to ~18 mW, with ~5 mW of idler power at 2670 nm, for 2 W of input pump power. The OPG exhibits a passive stability in total output power better than 0.87% rms over 1 hour, at a crystal temperature of 120 ºC, compared to 0.14% rms for the input pump. The output signal pulses, recorded at 1769 nm, have duration of 5.9 ns for input pump pulses of 9 ns. Temperature-dependent loss measurements for the pump polarization along the [100] axis in the OP-GaP crystal have also been performed, for the first time, indicating a drop in transmission from 28.8% at 50ºC to 19.4% at 160ºC. © 2015 Optical Society of America OCIS codes : (190.4360) Nonlinear optics, devices; (190.4400) Nonlinear optics, materials; (190.4410 Mid-infrared (mid-IR) coherent sources based on optical parametric down-conversion are of great significance for a variety of applications such as spectroscopy [1], up-conversion imaging [2] and as pump source for other nonlinear processes [3]. Oxide-based nonlinear crystals, and especially their quasi-phase matched (QPM) counterparts such as MgO-doped periodically-poled LiNbO3 (MgO:PPLN), stoichiometric LiTaO3 (MgO:sPPLT) and KTiOPO4 (PPKTP), have enabled broadband mid-IR coverage up to ~4 μm, in all time-scales from continuous-wave (CW) to femtosecond domain [4][5][6][7]. However, the onset of multiphonon absorption in these nonlinear crystals has been a fundamental barrier to reach spectral regions into the deep mid-IR. Non-oxide-based nonlinear materials with extended transparency in the mid-IR, such as ZnGeP2 (ZGP) and orientation-patterned GaAs (OP-GaAs), offer potential for the development of parametric sources beyond 4 μm. However, their low bandgap requires pumping beyond 2 μm to avoid two-photon absorption. The more recently developed nonlinear crystal, CdSiP2 (CSP), is an important new addition to the family of birefringent nonlinear materials for parametric downconversion into the deep mid-IR. The high optical nonlinearity, noncritical phase-matching (NCPM) capability, and a wide transparency range extending down to below ~1 μm, enable the deployment of the widely available Nd-based solid-state or Ybbased fiber lasers as pump source for deep mid-IR wavelength generation up to ~7 μm [8,9]. On the other hand, the new semiconductor nonlinear material, orientation-patterned GaP (OPGaP) can be considered as the QPM analog of CSP, and a promising alternative for deep mid-IR generation. As a QPM material, OP-GaP offers unique flexibility for tunable wavelength generation into the deep mid-IR using grating engineering under NCPM with no spatial walk-off. Moreover, unlike ZGP and OP-GaAs, it has sig...