2012
DOI: 10.1016/j.jpowsour.2011.12.048
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Nanoscale size effect of titania (anatase) nanotubes with uniform wall thickness as high performance anode for lithium-ion secondary battery

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Cited by 69 publications
(57 citation statements)
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“…Though the application of ALD in electrochemical storage is overwhelming, but till now the use is mostly limited to the protection layer to enhance the electrochemical performance of the electrode [22][23][24][25][26][27]. In recent literature, ALD was used to produce thin films of active material for lithium ion battery application [28][29][30][31][32]. TiO 2 was mostly studied system in this category [28,31,32].…”
Section: Introductionmentioning
confidence: 99%
“…Though the application of ALD in electrochemical storage is overwhelming, but till now the use is mostly limited to the protection layer to enhance the electrochemical performance of the electrode [22][23][24][25][26][27]. In recent literature, ALD was used to produce thin films of active material for lithium ion battery application [28][29][30][31][32]. TiO 2 was mostly studied system in this category [28,31,32].…”
Section: Introductionmentioning
confidence: 99%
“…It is well known that nano-morphology can endow TiO 2 with large surface area and thus high performances. For example, 3D ordered hollow TiO 2 nanotube arrays via facile anodization have been applied as the anode material in LIB [12], besides photo catalysts [13], solar cells [14], hydrogen sorption [15] and biomedical materials [16]. Because TiO 2 nanotubes arrays can act as excellent host for electrons and Li þ ions, and the tight combination with Ti substrate can allow for excluding of additional binder and conductive agent.…”
Section: Introductionmentioning
confidence: 99%
“…The selection of materials is quite a bit more limited than in the cathode case, most likely illustrating the consensus that improvements in battery energy density are more easily obtained with improved cathode materials. ALD-made TiO 2 has been studied as an anode material mostly in various 3D-constructions, illustrating the conformal coating ability of ALD [78,[96][97][98]. Using 3D-structures the areal capacity of the titania anode can be greatly improved [96,97] Generally, TiO 2 can intercalate 0.5 Li, resulting in a capacity of 170 mAh/g [97] However, using nanomaterials more lithium can be intercalated and capacities of 330 mAh/g have been obtained with anatase nanotubes with a wall thickness of 5 nm [98].…”
Section: Methodsmentioning
confidence: 99%