“…Beyond any possible doubt, Silicon is a fundamental material of utmost importance for both applicative purposes and pure science [ 1 ]. In this context, recent research activity shows a growing interest in the area of hybrid, silicon-based, molecular electronics, which is driven by possible technological applications such as biosensors, photovoltaic cells, and optoelectronic devices [ 2 , 3 , 4 , 5 , 6 ]. Different methodologies exist for the preparation of hybrid silicon-based interfaces, relying on the covalent grafting of organic molecules, and these are generally based on ultra-high vacuum (UHV) depositions [ 7 , 8 , 9 ], wet chemistry exploiting UV curing [ 10 , 11 ], electrochemical-based methodologies [ 12 , 13 ].…”