Nanoscale polymer encapsulated pigment hybrid latexes with high pigment content for binder-free pigment printing of cotton/polyester blend fabrics

Xie, Ziwen; Fen-ping, Wang; Li, Jiawei; Cui, Niuniu; Lin, Lu‐Yin; Lu, Hailiang; Yan, Xiaofei; Qi, Dongming

doi:10.1016/j.colsurfa.2022.130107

Cited by 9 publications

(10 citation statements)

References 41 publications

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“…The absorption peaks at 3017, 1943, 1864, and 1801 cm –1 were assigned to stretching vibration absorption peaks of C–H on the benzene ring . The peaks at 2920 and 2845 cm –1 were assigned to the stretching vibration of C–H on the St, BA, and AHAQ . Besides, a weak stretching vibration absorption at the peak of 1683 cm –1 was assigned to −CO of BA, and AHAQ .…”

Section: Resultsmentioning

confidence: 99%

“…31 The peaks at 2920 and 2845 cm −1 were assigned to the stretching vibration of C−H on the St, BA, and AHAQ. 32 Besides, a weak stretching vibration absorption at the peak of 1683 cm −1 was assigned to −C�O of BA, and AHAQ. 22 The two peaks at 751 and 696 cm −1 were typical absorption peaks of substituted benzene.…”

Section: Preparation and Characterization Of Clp@psmentioning

confidence: 99%

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Ink-Jet Printing of Colored Latex Inks with a “Soft” Core–“Hard” Shell Structure

Yang

Yin

Sheng

et al. 2023

ACS Appl. Polym. Mater.

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Colored latex particles (CLPs) as a novel colorant have been widely applied to salt-free dyeing and printing due to their adjustable composition, brilliant colors, excellent durability, and small particle size. In this paper, the effects of glass-transition temperatures (T g) on the filterability of CLP inks were first studied, and the results showed that the CLP inks can be successfully filtered and ejected when the T g’s of CLP inks exceeded 48 °C. Based on our previous research, CLP (T g = 25 °C)-printed fabrics had excellent color fastness and a soft hand feel, while a stiff hand feel occurred with the increase of the T g. Herein, the CLPs with a core–shell structure (CLP@PS) were designed using CLPs (T g = 25 °C) as a “soft” core for ensuring the color fastness of printed fabrics and PS as a “hard” core for ensuring excellent filterability of inks. Transmission electron microscopy and dynamic light scattering indicated that the prepared particles had an obvious core–shell structure, and the particle size was 96 nm. To balance the filterability of inks and color fastness of printed fabrics, the encapsulated thickness was optimized at 20 nm by adjusting the amounts of styrene (St) and 2,2′-azobis(2-methylpropionamidine) dihydrochloride (AIBA). The flow rate and filtration time of CLP@PS inks were 8.9 mL/s, and 11 s, respectively. Finally, the CLP@PS inks were applied to ink-jet printing of cotton fabric. Compared with pigment ink-jet printing, CLP@PS-printed fabrics had a softer hand feel and better rubbing and washing fastness.

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Section: Resultsmentioning

confidence: 99%

Section: Preparation and Characterization Of Clp@psmentioning

confidence: 99%

Ink-Jet Printing of Colored Latex Inks with a “Soft” Core–“Hard” Shell Structure

Yang

Yin

Sheng

et al. 2023

ACS Appl. Polym. Mater.

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“…In this context, MXene-Agbased hybrid materials benefitted from both chemical and electromagnetic enhancement mechanisms. [27,[115][116][117][118] Ag@MXene is one of the best-performing SERS substrates, with an enhancement factor of 1.5 × 10 5 for MB and good stability when compared to other overpriced metals hybrids like Pd@MXene, and Au@MXene substrates. [27] Ti 3 C 2 T x MXene was used by Fang et al, to protect the layer and prevent Ag nanowire arrays from oxidizing.…”

Section: Mxene-ag Hybridsmentioning

confidence: 99%

2D MXenes as a Promising Candidate for Surface Enhanced Raman Spectroscopy: State of the Art, Recent Trends, and Future Prospects

Patra,

M. B.,

Manasa

et al. 2023

Adv Funct Materials

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Surface‐enhanced enhanced Raman spectroscopy (SERS) has emerged as a powerful analytical technique for ultrasensitive and label‐free detection of chemical species, with numerous applications in various fields. Recently, 2D MXenes, have evoked substantial intrigue as promising substrates for SERS. Hence, a comprehensive understanding of the developments in the Raman effect and the mechanisms involved in SERS is highly crucial. The review reflects the advances, working principle, and dual mechanisms, including SERS's electromagnetic and chemical mechanisms. Noble metal nanostructures are highly prioritized as SERS substrates owing to their excellent sensitivity. However, due to certain disadvantages that they pose, metal‐free SERS substrates with exceptional tunable properties are extensively researched in the current days. The combination of 2D MXenes and nanostructures can be effective in producing enhanced SERS signals. SERS performance of different MXene‐based materials is emphasized. The performance of this combination is credited to their large surface‐to‐volume ratio, good electrical conductivity, and surface‐terminated functionalities. The recent advancements in MXenes and MXenes‐based heterostructures driven SERS sensing concerning the structural design of the material, its performance, and the mechanisms are studied. Finally, a detailed conclusion is provided with the challenges and future perspectives for designing 2D materials for efficient SERS sensors.

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“…One strategy for improving the performance of pigment dyed/printed fabrics is binder-free pigment dyeing/printing of textiles using polymer/pigment hybrid latex. , Several studies have explored the use of emulsion polymerized copolymer-encapsulated pigment hybrid latex particles instead of blended pigment and adhesive latex. − These approaches control the size of pigment aggregation on the quasi-nanoscale and strongly anchor pigment particles in the latex film, as depicted in Figure b. Successful pigment hybrid latex has been reported, but the developed strategies require improvement of their textile pigment dyeing/printing performance to reach equality with the level of chemical dye coloring. , Typically, to further improve the hand-feeling, air-permeability, and other performances of printed fabric, polydimethylsiloxane (PDMS) has been incorporated into copolymer chains owing to its sufficiently low glass transition temperature ( T g ), excellent thermal stability, abrasion resistance, and weather durability. − In our earlier studies, to synthesize PDMS-modified PAcr/pigment hybrid latex, and improve the hand-feeling, air-permeability, and water-resistance of the pigment-printed polyester (PET) fabric, we utilized one-pot in situ mini-emulsion polymerization.…”

Section: Introductionmentioning

confidence: 99%

“…12 One strategy for improving the performance of pigment dyed/printed fabrics is binder-free pigment dyeing/printing of textiles using polymer/pigment hybrid latex. 13,14 Several studies have explored the use of emulsion polymerized copolymerencapsulated pigment hybrid latex particles instead of blended pigment and adhesive latex. 15−19 These approaches control the size of pigment aggregation on the quasi-nanoscale and strongly anchor pigment particles in the latex film, as depicted in Figure 1b.…”

Section: ■ Introductionmentioning

confidence: 99%

Film-Formation and Binder-Free Pigment Printing of Fluorosilicone-Modified Polyacrylate/Pigment Hybrid Latex: Effect of Cross-Linking Degree

Lin

Duan

et al. 2023

ACS Appl. Polym. Mater.

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Binder-free pigment dyeing/printing of textiles is a type of environmentally friendly and clean production technology that utilizes polymer/pigment hybrid latex. Although it has widespread use, the manner in which the nature of the hybrid latex influences the film formation and how systems can be designed to improve softness and air-permeability is still unclear. In this study, we synthesized a series of fluorosilicone-modified polyacrylate/pigment hybrid latexes to explore how cross-linking degree affects film-formation behavior and binder-free pigment printing performance on fabric, where the cross-linking structure is controlled by a silane coupling agent. Our results show that the cross-linking degree of the fluorosilicone-modified polyacrylate chain plays a vital role in chain diffusion, latex particle packing, and deformation. Further, it controls "skin" formation during the process of hybrid latex drying. The dried hybrid films not only have homogeneity and good barrier performance but also exhibit a soft state (low T g , − 28.3 °C) owing to the silicone chain segment and bound water with a plasticizing effect. Interestingly, our results show that the cross-linking degree of hybrid latex particles changes as a function of the morphology of the printed polyester (PET) fiber. Further, as a result of the improvement of the softness and airpermeability of the binder-free printed PET fabric, the surface of single yarns is uniformly wrapped by hybrid films with a high crosslinking degree. These insights allow for effective development of textile pigment printing technology controlled by the film-formation behavior of hybrid latex.

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Nanoscale polymer encapsulated pigment hybrid latexes with high pigment content for binder-free pigment printing of cotton/polyester blend fabrics

Cited by 9 publications

References 41 publications

Ink-Jet Printing of Colored Latex Inks with a “Soft” Core–“Hard” Shell Structure

Ink-Jet Printing of Colored Latex Inks with a “Soft” Core–“Hard” Shell Structure

2D MXenes as a Promising Candidate for Surface Enhanced Raman Spectroscopy: State of the Art, Recent Trends, and Future Prospects

Film-Formation and Binder-Free Pigment Printing of Fluorosilicone-Modified Polyacrylate/Pigment Hybrid Latex: Effect of Cross-Linking Degree

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