“…The analysed sample comes from an area of the glass fragment where the surface patina is thicker. The fragment was embedded in epoxy resin (epoxy resin and slow cure hardener PELCO, Ted Pella) and thin sections were prepared using the same protocol employed by Beltran et al 21 Thin sections with thicknesses of 3.5 μm and 100 nm were cut using an ultramicrotome (Leica EM UC6) equipped with a 45° diamond knife (Diatome Histo, Leica, HI 7177). Subsequently, the 3.5 μm thin section was placed on pellets made with KBr (Sigma Aldrich, 221864-M FT-IR grade), to facilitate manipulation, while the 100 μm one was directly deposited on a TEM copper grid to perform TEM analysis.…”