2021
DOI: 10.1021/acsanm.1c01952
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Nanometer-Scale Molecular Cluster Surfactants Generate Robust Gel Emulsion Systems for Solid-State Electrolytes

Abstract: Pickering emulsions stabilized by colloidal particles or their mixtures with surfactants have received increasing interest in recent years, but few of them can produce gel emulsions with practical stability. Herein, robust gel emulsions can be facilely prepared through the charge attraction-driven complexation and enrichment of negatively charged coordination nanocages (CNCs) and cationic surfactants at liquid/liquid interfaces. Due to CNCs' ultrasmall sizes (∼2.5 nm) and highly charged features, they strongly… Show more

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Cited by 3 publications
(2 citation statements)
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“…The well-defined structures of CNCs facilitate the precise chemical tailoring on CNC surfaces, providing great opportunities for the covalent and/or noncovalent functionalization of CNCs with required functional groups. [7][8][9] This finally enables the further processing of CNCs into functional materials through their assembly or integration into colloid nanoparticles (NPs), 10 membranes [11][12][13] or porous framework. [14][15][16] Generally, covalent bonding or strong coordination bonding is applied to ensure the robust formation and stability of the network structures of gels.…”
Section: Introductionmentioning
confidence: 99%
“…The well-defined structures of CNCs facilitate the precise chemical tailoring on CNC surfaces, providing great opportunities for the covalent and/or noncovalent functionalization of CNCs with required functional groups. [7][8][9] This finally enables the further processing of CNCs into functional materials through their assembly or integration into colloid nanoparticles (NPs), 10 membranes [11][12][13] or porous framework. [14][15][16] Generally, covalent bonding or strong coordination bonding is applied to ensure the robust formation and stability of the network structures of gels.…”
Section: Introductionmentioning
confidence: 99%
“…First of all, because gel emulsions have special internal structures, which can be tuned by varying the compositions of the continuous phase and the content of the dispersed phase, the impedance matching characteristics can be adjusted easily by changing the content of the dispersed phase. [46][47][48][49][50][51] There are many applications for the gel method to prepare other materials. [52][53][54][55] Moreover, the dispersed phase of gel emulsions is usually water rather than organic solvents, which is more environmentally friendly and reduces the cost.…”
Section: Introductionmentioning
confidence: 99%