Nanoengineering of Thin Film V2O5 Cathode Interfaces via Atomic Layer Deposition for use with Polymer Gel Ionic Liquid Electrolytes
Aaron O'Donoghue,
Micheál Shine,
Ian M. Povey
et al.
Abstract:In this work we show high capacity and cycle‐life performance, for electrodeposited, crystalline V2O5 thin film cathodes protected by a 1 nm ALD alumina deposit for use with Li‐metal and ionic liquid electrolyte based microbatteries. Al2O3 coatings thicker than 1 nm are shown to decrease the performance of the V2O5 thin film cathodes. The ionic liquid outperforms an organic electrolyte at 1 C rates with an initial capacity of 148 mAh g‐1 and capacity retention of 97% at cycle 50. A polymer gel analogue of the … Show more
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