2004
DOI: 10.1021/nl048776b
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Nanocarpet Effect:  Pattern Formation during the Wetting of Vertically Aligned Nanorod Arrays

Abstract: When a water droplet spreads on a vertically aligned nanorod surface, the nanorod array will deform into statistically percolated patterns. This nanocarpet effect has been investigated for Si nanorods. Three distinct morphologies were found: a center region due to the water droplet impact, a tilting region due to gravity, and a percolation region due to capillary invasion. The corresponding capillary forces have been estimated through finite element analysis. This effect presents a challenge for nanodevices in… Show more

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Cited by 129 publications
(136 citation statements)
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“…The hydrophilicity of NWs and CNTs with water has been widely reported in the literature [13,[17][18][19]. Sessile-drop experiments performed by Ebbesen [20] with water on a CNT bundle showed complete wetting of the capillary channels between nanotubes.…”
Section: Introductionmentioning
confidence: 84%
“…The hydrophilicity of NWs and CNTs with water has been widely reported in the literature [13,[17][18][19]. Sessile-drop experiments performed by Ebbesen [20] with water on a CNT bundle showed complete wetting of the capillary channels between nanotubes.…”
Section: Introductionmentioning
confidence: 84%
“…The pores of nanowire arrays also have a high capillary pressure; however, their relative impermeability compared to microscale wick structures must be carefully assessed in the design process. Further, while the hydrophilicity of NWs and CNTs with water has been reported in the literature [205,206], aligned arrays of nanotubes have also been shown to behave as superhydrophobic surfaces [207]. Hence, surfactants may be used for liquid conveying applications [208], or nanostructures may be functionalized for heat transfer applications via metallization [51], hydrochloric acid treatment [209], or ultraviolet excitation [210].…”
Section: Nanostructured Capillary Wicks For Vapor Chamber Applicationsmentioning
confidence: 99%
“…At an aspect ratio (h/2r) of 25 and a packing density p= 50% for the nanopillars, a 51-fold increase in surface area can be achieved. To date, various 3D skyscraper nanostructures have been fabricated using chemical vapor deposition (CVD) (Lau et al, 2003), physical vapor deposition (PVD) (Fan et al, 2004) and template based electrodeposition (Forrer et al, 2000;Wang et al, 2002;Xu et al, 2004). Lately, evidence has emerged to reveal that the nanotubes and nanorods developed by the CVD and PVD techniques could not sustain the capillary forces generated by the nanostructureliquid interaction (Lau et al, 2003;Fan et al, 2004).…”
Section: Design Of High-surface-area Nanostructuresmentioning
confidence: 99%