Angew. Chem.
 2002
DOI: 10.1002/1521-3757(20020517)114:10<1777::aid-ange1777>3.0.co;2-z
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Na3N - ein origineller Syntheseweg für ein lange gesuchtes binäres Nitrid

Rainer Niewa
1

Abstract: Versteckspiel beendet: Nachdem über die Existenz eines binären Natriumnitrids Na3N lange Zeit spekuliert worden war, gelang nun Fischer und Jansen durch ein neuartiges experimentelles Verfahren die Synthese und strukturelle Charakterisierung dieser im anti‐Re3O‐Strukturtyp kristallisierenden Verbindung (siehe Struktur).

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