N2 in ZIF-8: Sorbate induced structural changes and self-diffusion

Chokbunpiam, T.; Chanajaree, Rungroj; Remsungnen, Tawun; Saengsawang, Oraphan; Fritzsche, Siegfried; Chmelik, Christian; Caro, Jürgen; Janke, Wolfhard; Hannongbua, Supot

doi:10.1016/j.micromeso.2013.12.012

Cited by 30 publications

(25 citation statements)

References 40 publications

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“…This was first followed in the area of adsorption, where increasing concentrations of gases or liquids inside the pores lead to structural transitions. Such transitions have been labeled as gate opening12 or breathing 8. In such systems, even though calorimetric measurements have been carried out, it is impossible to deconvolute the heats that are due to host–guest interactions and those due to the host framework transition.…”

Section: Experimental Energy Data Of Compression–decompression Cyclesmentioning

confidence: 99%

The Direct Heat Measurement of Mechanical Energy Storage Metal–Organic Frameworks

et al. 2015

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International audienceIn any process, the heat exchanged is an essential property required in its development. Whilst the work related to structural transitions of some flexible metal-organic frameworks (MOFs) has been quantified and linked with potential applications such as molecular springs or shock absorbers, the heat related to such transitions has never been directly measured. This has now been carried out with MIL-53(Al) using specifically devised calorimetry experiments. We project the importance of these heats in devices such as molecular springs or dampers

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Section: Experimental Energy Data Of Compression–decompression Cyclesmentioning

confidence: 99%

The Direct Heat Measurement of Mechanical Energy Storage Metal–Organic Frameworks

et al. 2015

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“…The first separating ZIF membranes were synthesized with ZIF-8 [23]. The experimental studies were accompanied by a variety of molecular simulations to provide insight into the underlying mechanism on the atomistic scale [16,[24][25][26][27][28][29][30][31].…”

Section: Introductionmentioning

confidence: 99%

Characteristic features of molecular transport in MOF ZIF-8 as revealed by IR microimaging

Chmelik

2015

Microporous and Mesoporous Materials

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“…306,[323][324][325][326] There are some recent reports that the framework adsorbs bulky molecules such as benzene or xylenes, 327,328 despite its pore openings of 3.4 Å as found from Rietveld XRD analysis. Hence, it is possible that adsorbed molecules can ''open the gate'' under certain conditions, [329][330][331][332][333][334][335][336][337] as illustrated in Fig. 13.…”

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confidence: 99%

Zeolite membranes – a review and comparison with MOFs

et al. 2015

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aThe latest developments in zeolite membranes are reviewed, with an emphasis on the synthesis techniques, including seed assembly and secondary growth methods. This review also discusses the current industrial applications of zeolite membranes, the feasibility of their use in membrane reactors and their hydrothermal stability. Finally, zeolite membranes are compared with metal-organic framework (MOF) membranes and the latest advancements in MOF and mixed matrix membranes are highlighted.

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N2 in ZIF-8: Sorbate induced structural changes and self-diffusion

Cited by 30 publications

References 40 publications

The Direct Heat Measurement of Mechanical Energy Storage Metal–Organic Frameworks

The Direct Heat Measurement of Mechanical Energy Storage Metal–Organic Frameworks

Characteristic features of molecular transport in MOF ZIF-8 as revealed by IR microimaging

Zeolite membranes – a review and comparison with MOFs

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