Abstract:Amino alcoholsAmino alcohols P 0130 N-Silyl-Tethered Radical Cyclizations: A New Synthesis of γ-Amino Alcohols. -Reaction of N-protected allylamines with the silyl chloride (II) generates bromomethylsilylamines which are subjected to radical cyclization followed by Tamao oxidation. The use of the Boc-protecting group gives the best yield of the corresponding γ-amino alcohol. -(BLASZYKOWSKI, C.; DHIMANE, A.-L.; FENSTERBANK, L.; MALACRIA*, M.; Org. Lett. 5 (2003) 8, 1341-1344; Lab. Chim. Org., CNRS, Univ. P. et … Show more
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