N,N′‐Pentamethylenethiuram disulfide and N,N′‐pentamethylenethiuram hexasulfide accelerated sulfur vulcanization. III. Vulcanization of polyisoprene and 2,3‐dimethyl‐2‐butene in the absence of ZnO
Abstract:Polyisoprene and model compound, 2,3-dimethyl-2-butene, were vulcanized with N,NЈ-dipentamethylenethiuram disulfide (CPTD), CPTD/sulfur and N,NЈ-dipentamethylenethiuram hexasulfide (CPTP6) in the absence of ZnO and residual extractable curatives and reaction intermediates analyzed by HPLC at various stages of the reaction. Accelerator polysulfides, required for the formation of accelerator-terminated polysulfidic pendent groups, form rapidly, or are present from the outset in the case of CPTP6. Model compounds… Show more
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