N-methylpyrrolidine-2-one hydrotribromide: An efficient and new catalyst for the aziridination of alkenes using Chloramine-T under solvent free conditions

Jain, Suman L.; Joseph, Jomy K.; Sain, Bir

doi:10.1016/j.molcata.2006.04.029

Cited by 13 publications

(2 citation statements)

References 25 publications

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“…For this purpose Chloramine T has been used in the presence of various catalysts (Scheme 127) [166][167][168][169][170][171][172]. For this purpose Chloramine T has been used in the presence of various catalysts (Scheme 127) [166][167][168][169][170][171][172].…”

Section: Scheme 126mentioning

confidence: 99%

Application of N-halo reagents in organic synthesis

Kolvari

Ghorbani‐Choghamarani

Salehi

et al. 2007

JICS

157

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This review article summarizes published data on the application of N-halo reagents (such as N-halo amines, N-halo amides and/or imides, N-halo sulfonamides and/or imides, and etc.) in various organic functional group transformations such as: oxidation reactions, deprotection and protection of different functional groups, halogenation of saturated and unsaturated compounds, acylation of alcohols, phenols, amines or thiols, epoxidation of alkenes, aziridination and etc. The main purpose of writing this review is encouraging of active researchers interested to this field for the synthesis of new N-halo reagents specially with different halogens and applications of these new N-halo reagents in organic reactions or finding more and more applications of existing N-halo reagents in organic synthesis.

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Section: Scheme 126mentioning

confidence: 99%

Application of N-halo reagents in organic synthesis

Kolvari

Ghorbani‐Choghamarani

Salehi

et al. 2007

JICS

157

View full text Add to dashboard Cite

show abstract

“…The inexpensive, environmentally benign chloramine-T hydrate (TolSO 2 NNaCl·H 2 O) has received some attention as a reagent for olefin aziridination and ether α-amidation under catalysis by CuCl or Cu[tris ( pyrazolylborate)] . Only a few examples of benzylic amidation with this reagent have been reported, with modest yields and variable regioselectivity. , In search of more efficient and economical systems for the selective amidation of C−H bonds, we have examined the copper-catalyzed reactions of anhydrous chloramine-T with representative benzylic and allylic hydrocarbons and ethers.…”

mentioning

confidence: 99%