N‐Heterocyclic Olefin‐Phosphines Based Cationic Ruthenium Complexes as Pre‐Catalysts for Dual C−H Bond Functionalizations
Amiya Kumar Sahoo,
Bhagyashree Das,
Subhra Jyoti Panda
et al.
Abstract:Two N‐heterocyclic olefin‐phosphines and the corresponding ruthenium complexes were synthesized and structurally characterized. One of the cationic complexes [(BzIM)(NHOP)Ru(p‐cymene)Cl2]I was employed as a catalyst in N‐benzylbenzamides/alkyne coupling reactions. With this catalytic protocol a variety of substituted isoquinolones were synthesized through ortho‐selective double C‐H bond functionalization involving oxidative annulation followed by olefination reactions. All these products were achieved in one‐p… Show more
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