2022
DOI: 10.1016/j.cej.2021.132824
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N-doped CNT as electron transport promoter by bridging CoP and carbon cloth toward enhanced alkaline hydrogen evolution

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Cited by 47 publications
(20 citation statements)
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“…For the high-resolution Co 2p core-level spectrum of CoP/CeO x -20:1 in Figure 4b, the deconvoluted peaks are ascribed to the Co 2p 3/2 peaks region at the binding energies of 778.89, 781.63, and 785.50 eV (satellite peak), and the peaks of 793.88 and 797.76 eV and satellite peak at 802.66 eV are assigned to the Co 2p 1/2 region. 21,37,38 Furthermore, the two peaks located at 778.89 and 793.88 eV are attributed to Co−P species, while the other peaks correspond to Co 2+ owing to superficial oxidation of phosphide. 39 Moreover, all of the characteristic peaks are shifted toward lower binding energies compared to pure CoP, which indicates the charge redistribution and electron transfer from amorphous CeO x to CoP.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
“…For the high-resolution Co 2p core-level spectrum of CoP/CeO x -20:1 in Figure 4b, the deconvoluted peaks are ascribed to the Co 2p 3/2 peaks region at the binding energies of 778.89, 781.63, and 785.50 eV (satellite peak), and the peaks of 793.88 and 797.76 eV and satellite peak at 802.66 eV are assigned to the Co 2p 1/2 region. 21,37,38 Furthermore, the two peaks located at 778.89 and 793.88 eV are attributed to Co−P species, while the other peaks correspond to Co 2+ owing to superficial oxidation of phosphide. 39 Moreover, all of the characteristic peaks are shifted toward lower binding energies compared to pure CoP, which indicates the charge redistribution and electron transfer from amorphous CeO x to CoP.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
“…There are two obvious Raman peaks located at 1340 and 1570 cm –1 , which belong to carbon atoms. The peak at 1340 cm –1 corresponds to the D-band, and the peak intensity is related to the edge defects and disorder degree of the carbon sample . The peak at 1570 cm –1 corresponds to the G-band, which is related to the order degree of sp carbon atoms and reflects the graphitization degree .…”
Section: Resultsmentioning
confidence: 99%
“…The peak at 1340 cm −1 corresponds to the Dband, and the peak intensity is related to the edge defects and disorder degree of the carbon sample. 19 The peak at 1570 cm −1 corresponds to the G-band, which is related to the order degree of sp 2 carbon atoms and reflects the graphitization degree. 28 From the Raman spectra of bare CFM, the intensity of peaks D and G is weak, and their full width at half-maximum (fwhm) is wide.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
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“…[33][34][35] The post-in-situ synthetic pathway provides a new approach for achieving continuous and nanoscaled contact between conductive agent and catalytic materials, which is expected to reduce the interface resistance with a binder-free structure. [36,37] The feasibility of in-situ polymerization of PPy nanowires on active materials for metal-gas batteries has not yet been explored. Meanwhile, the PPy nanofibers can physically assemble to form a flexible freestanding film, which bypasses the complicated preparation process of traditional cathodes.…”
Section: Introductionmentioning
confidence: 99%