2022
DOI: 10.1002/aenm.202202860
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MXenes for Sulfur‐Based Batteries

Abstract: Sulfur‐based batteries are regarded as potent candidates for next‐generation high‐energy and low‐cost energy storage systems. However, sulfur‐based batteries still face substantial obstacles on the cathode side (e.g., low conductivity and sluggish reaction kinetics of sulfur) and the anode side (e.g., dendrite growth), severely hindering their utilization. MXenes (i.e., 2D transition metal carbides, nitrides, and carbonitrides), as an emerging member of the 2D material family, possess unique electrochemical an… Show more

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Cited by 42 publications
(30 citation statements)
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“…When used in lithium-sulfur batteries, MXene can improve their cycling performance. ( Wang et al, 2023 ). MXene can be used in photocatalytic field by schottky junctions and heterojunctions ( Xi et al, 2023 ).…”
Section: Introductionmentioning
confidence: 99%
“…When used in lithium-sulfur batteries, MXene can improve their cycling performance. ( Wang et al, 2023 ). MXene can be used in photocatalytic field by schottky junctions and heterojunctions ( Xi et al, 2023 ).…”
Section: Introductionmentioning
confidence: 99%
“…Among them, heterostructures are used to construct coating layer to endow the separator more functions. [205][206][207][208] These heterostructures based coating layer usually has enough space to ensure the efficient Li + transport. In addition, the solvation radius of Li + is usually <0.5 nm in organic solvents, which is small enough compared to the gap of coating layer.…”
Section: Heterostructure For Separator Modificationmentioning
confidence: 99%
“…First, the insulating nature of both sulfur (5 × 10 −28 S cm −1 ) or selenium (1 × 10 −3 S cm −1 ), as well as their discharge products lead to the poor electrode conductivity. [83,84] Second, the notable volume change of the chalcogen cathode (e.g., 50.3% of S) during battery dynamic cycling may induce a large mechanical destruction effect. [85,86] Third, the sluggish reaction kinetics of chalcogen species during the direct solid-solid conversion process in water-based electrolyte may bring low energy efficiencies during cycles.…”
Section: Issues Of Aqueous Zinc-chalcogen Batteriesmentioning
confidence: 99%