Mxene Quantum Dot Nanosurface Molecularly Imprinted Polymer Resonance Rayleigh Scattering Probe for Highly Sensitive and Selective Determination of Thiocyanate

Abstract

In this article, a nanosurface molecularly imprinted polymer (MQD@MIP) resonance Rayleigh scattering (RRS) spectral probe for SCN − was prepared by sol−gel method, using Mxene quantum dot as a matrix, thiocyanate (SCN − ) as a template ion, (3-aminopropyl) triethoxysilane (APTES) as a functional monomer, tetraethoxysilane (TEOS) as the crosslinker, and ammonia as the initiator. The probe produced an RRS peak at 370 nm and exhibits a strong RRS energy transfer (RRS-ET) effect when the MQD@MIP probe identifies SCN − . As the concentration of SCN − increased, the RRS-ET was enhanced, and the signal value of the system decreased linearly at 370 nm, with a determination range of 0.87−5.22 μg/L, and a detection limit of 0.37 μg/L SCN − . This detection method has the characteristics of simplicity, sensitivity, and specific recognition. The RRS method was used to determine SCN − in the sample, with relative standard deviation of 1.95−10.98% and recovery of 89.0−102.8%.