The doublet capture rate Λ 1/2 of the negative muon capture in deuterium is calculated employing the nuclear wave functions generated from accurate nucleon-nucleon (NN) potentials constructed at next-to-next-to-next-to-leading order of heavy-baryon chiral perturbation theory and the weak meson exchange current operator derived within the same formalism. All but one of the lowenergy constants that enter the calculation were fixed from pion-nucleon and nucleon-nucleon scattering data. The low-energy constantd R (c D ), which cannot be determined from the purely two-nucleon data, was extracted recently from the triton β-decay and the binding energies of the three-nucleon systems. The calculated values of Λ 1/2 show a rather large spread for the used values of thed R . Precise measurement of Λ 1/2 in the future will not only help to constrain the value ofd R , but also provide a highly nontrivial test of the nuclear chiral EFT framework. Besides, the precise knowledge of the constantd R will allow for consistent calculations of other two-nucleon weak processes, such as proton-proton fusion and solar neutrino scattering on deuterons, which are important for astrophysics.