Multiplying Oxygen Permeability of a Ruddlesden‐Popper Oxide by Orientation Control via Magnets
Zhijun Zhao,
Guoxing Chen,
Giamper Escobar Cano
et al.
Abstract:Ruddlesden‐Popper‐type oxides exhibit remarkable chemical stability in comparison to perovskite oxides. However, they display lower oxygen permeability. We present an approach to overcome this trade‐off by leveraging the anisotropic properties of Nd2NiO4+δ. Its (a,b)‐plane, having oxygen diffusion coefficient and surface exchange coefficient several orders of magnitude higher than its c‐axis, can be aligned perpendicular to the gradient of oxygen partial pressure by a magnetic field (0.81 T). A stable and high… Show more
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