1996
DOI: 10.1016/0022-328x(95)05865-m
|View full text |Cite
|
Sign up to set email alerts
|

Multiply substituted cyclopentadienyl metal complexes: I. Solid-state and solution conformational studies on

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
2

Citation Types

0
6
0

Year Published

1997
1997
2019
2019

Publication Types

Select...
7

Relationship

0
7

Authors

Journals

citations
Cited by 10 publications
(6 citation statements)
references
References 46 publications
0
6
0
Order By: Relevance
“…Synthesis of [Zn(C 5 Me 4 t Bu)) 2 ] (3), [Zn(C 5 Me 4 SiMe 2 t Bu) 2 ] (4) and [Zn(C 5 Me 4 SiMe 3 ) 2 ] (5): These compounds were prepared by reaction of ZnCl 2 and MCp′ in THF, at room temperature, for a period of about 3 h (M=K, Cp′=C 5 Me 4 t Bu for 3 ;53 M=Li, Cp′=C 5 Me 4 SiMe 2 t Bu for 4 ;54 M=K, Cp′=C 5 Me 4 SiMe 3 for 5 ;52b). After removal of the volatiles in vacuo the residue was dissolved in hexane and the solutions filtered.…”
Section: Methodsmentioning
confidence: 99%
“…Synthesis of [Zn(C 5 Me 4 t Bu)) 2 ] (3), [Zn(C 5 Me 4 SiMe 2 t Bu) 2 ] (4) and [Zn(C 5 Me 4 SiMe 3 ) 2 ] (5): These compounds were prepared by reaction of ZnCl 2 and MCp′ in THF, at room temperature, for a period of about 3 h (M=K, Cp′=C 5 Me 4 t Bu for 3 ;53 M=Li, Cp′=C 5 Me 4 SiMe 2 t Bu for 4 ;54 M=K, Cp′=C 5 Me 4 SiMe 3 for 5 ;52b). After removal of the volatiles in vacuo the residue was dissolved in hexane and the solutions filtered.…”
Section: Methodsmentioning
confidence: 99%
“…Fe(CO) 5 was used as supplied from Aldrich chemicals. Compound 2 , (C 5 Me 5 )Fe(CO) 2 I, (C 5 Me 4 H)Fe(CO) 2 I, 1 and C 5 Me 4 H 2 were all prepared according to literature methods.…”
Section: Methodsmentioning
confidence: 99%
“…Dehydrated solvent was used in the reaction. HCp *Ethyl (5-ethyl-1,2,3,4-tetramethylcyclopentadiene) [65], HCp *iPr (5-isopropyl-1,2,3,4-tetramethylcyclopentadiene) [64,65], HCp *tBu (5-tert-butyl-1,2,3,4tetramethylcyclopentadiene) [66], (Cp*Ir(6,6'-dihydroxy-2,2'-bipyridine)Cl)Cl (2b) [ [a] Conversion and yields were determined by GC using biphenyl as internal standard.…”
Section: Generalmentioning
confidence: 99%
“…Dehydrated solvent was used in the reaction. HCp *Ethyl (5-ethyl-1,2,3,4-tetramethylcyclopentadiene) [65], HCp *iPr (5-isopropyl-1,2,3,4tetramethylcyclopentadiene) [64,65], HCp *tBu (5-tert-butyl-1,2,3,4-tetramethylcyclopentadiene) [66], (Cp*Ir(6,6 -dihydroxy-2,2 -bipyridine)Cl)Cl (2b) [67], Cp*Ir(2.2 -bipyridine-6,6 -dionato)H 2 O (3b) [40], and 6,6 -dihydroxy-2,2 -bipyridine [68] were prepared according to the literature method. All other reagents are commercially available and were used as received (FUJIFILM Wako Pure Chemical Corp., Osaka, Japan); (Nacalai Tesque, Kyoto, Japan); (Tokyo Chemical Industry Co., Ltd., Tokyo, Japan).…”
Section: Generalmentioning
confidence: 99%
See 1 more Smart Citation