Multiple ethylene activation by heteroleptic L(Cl)Ga-substituted germylenes
Anna Bücker,
Christoph Wölper,
Hannah Siera
et al.
Abstract:L(Cl)Ga-substituted germylenes react with ethylene with insertion into the Ga–Ge bonds to digermenes, which undergo [2 + 2] cycloaddition with ethylene to give 1,2-digermacyclobutanes.
The electron-rich germylene LGa(μ–Cl)GeArMes 1 (L = CH[C(Me)N(Dipp)]2, Dipp = 2,6-iPr2C6H3, ArMes = 2,6-Mes2C6H3, Mes = 2,4,6-Me3C6H2) shows promising potential in the σ-bond activation of unpolar molecules as is shown...
The electron-rich germylene LGa(μ–Cl)GeArMes 1 (L = CH[C(Me)N(Dipp)]2, Dipp = 2,6-iPr2C6H3, ArMes = 2,6-Mes2C6H3, Mes = 2,4,6-Me3C6H2) shows promising potential in the σ-bond activation of unpolar molecules as is shown...
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