Abstract:Interfaces play a critical role in the properties and lifetime of current generation and advanced batteries. However, detailed characterization of the critical interfaces during battery operation which can enable performance improvements and improved design has been a significant challenge requiring innovative technique development and creative experiments. This paper describes ways that information from a range of microscopy, spectroscopy, and spectrometry tools can be used to address important challenges ass… Show more
“…The nature of sample handling, the time between preparation and analysis, and environmental factors can all impact an analysis. 49, 92, 93 Some samples require handling in a glove box, 92, 94 some may require heating in vacuum to get to the desired state, 92, 95 while others may need cooling to avoid sample alteration or probe damage. 6, 96 XPS data can also be collected in a variety of modes, each with relevant protocols and considerations, 11 including survey (wide scan) spectra, selected-region high energy resolution (narrow scan) spectra, imaging, 88, 97 angle resolved 98 and sometimes the use of ion sputtering for depth profiling.…”
Section: Can Xps Provide the Information I Need?mentioning
Over the past three decades, the widespread utility and applicability of X-ray photoelectron spectroscopy (XPS) in research and applications has made it the most popular and widely used method of surface analysis. Associated with this increased use has been an increase in the number of new or inexperienced users which has led to erroneous uses and misapplications of the method. This article is the first in a series of guides assembled by a committee of experienced XPS practitioners that are intended to assist inexperienced users by providing information about good practices in the use of XPS. This first guide outlines steps appropriate for determining whether XPS is capable of obtaining the desired information, identifies issues relevant to planning, conducting and reporting an XPS measurement, and identifies sources of practical information for conducting XPS measurements. Many of the topics and questions addressed in this article also apply to other surface-analysis techniques.
“…The nature of sample handling, the time between preparation and analysis, and environmental factors can all impact an analysis. 49, 92, 93 Some samples require handling in a glove box, 92, 94 some may require heating in vacuum to get to the desired state, 92, 95 while others may need cooling to avoid sample alteration or probe damage. 6, 96 XPS data can also be collected in a variety of modes, each with relevant protocols and considerations, 11 including survey (wide scan) spectra, selected-region high energy resolution (narrow scan) spectra, imaging, 88, 97 angle resolved 98 and sometimes the use of ion sputtering for depth profiling.…”
Section: Can Xps Provide the Information I Need?mentioning
Over the past three decades, the widespread utility and applicability of X-ray photoelectron spectroscopy (XPS) in research and applications has made it the most popular and widely used method of surface analysis. Associated with this increased use has been an increase in the number of new or inexperienced users which has led to erroneous uses and misapplications of the method. This article is the first in a series of guides assembled by a committee of experienced XPS practitioners that are intended to assist inexperienced users by providing information about good practices in the use of XPS. This first guide outlines steps appropriate for determining whether XPS is capable of obtaining the desired information, identifies issues relevant to planning, conducting and reporting an XPS measurement, and identifies sources of practical information for conducting XPS measurements. Many of the topics and questions addressed in this article also apply to other surface-analysis techniques.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.