Multimetallic Complexes Based on a Diphosphine-Dithiocarbamate “Janus” Ligand

Sherwood, Rebecca; Rivera, Ferran Gonzàlez de; Wan, Jane Hui; Zhang, Qi; White, Andrew J. P.; Rossell, Oriol; Hogarth, Graeme; Wilton‐Ely, James D. E. T.

doi:10.1021/ic5028527

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Cited by 17 publications

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References 75 publications

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“…While protection/deprotection approaches offer a solution to this problem, an alternative, more synthetically straightforward option is to tailor bifunctional linkers to the metals involved (Chart ). This approach has been used by us and others to access molecular assemblies consisting of between two and six metals, encompassing compounds in which up to six different metals are combined…”

Section: Introductionmentioning

confidence: 99%

Bifunctional Chalcogen Linkers for the Stepwise Generation of Multimetallic Assemblies and Functionalized Nanoparticles

et al. 2016

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Section: Introductionmentioning

confidence: 99%

Bifunctional Chalcogen Linkers for the Stepwise Generation of Multimetallic Assemblies and Functionalized Nanoparticles

et al. 2016

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Synthesis and Application of Ruthenium(II) Alkenyl Complexes with Perylene Fluorophores for the Detection of Toxic Vapours and Gases

García‐Calvo

Robson

Torroba

et al. 2019

Chemistry A European J

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As eries of new ruthenium(II) vinyl complexes has been prepared incorporating perylenemonoimide (PMI) units. This fluorogenic moiety was functionalised with terminal alkyne or pyridyl groups,a llowing attachment to the metal either as av inyl ligand or through the pyridyln itrogen. The inherentl ow solubility of the perylene compounds was improved through the design of poly-PEGylated (PEG = polyethylene glycol)units bearing aterminal alkyne or apyridyl group. By absorbing the compounds on silica, vapours and gases could be detected in the solid state. The reaction of the complexes [Ru(CH=CH-Per Im )Cl(CO)(py-3PEG)(PPh 3 ) 2 ] and [Ru(CH=CH-3PEG)Cl(CO)(py-Per Im )(PPh 3 ) 2 ]w ith carbon monoxide, isonitrile or cyanide was found to result in modulation of the fluorescenceb ehaviour.T he complexes were observed to display solvatochromic effects andt he interaction of the complexes with aw ide range of other species was also studied. The study suggestst hat such complexes have potential for the detection of gases or vapourst hat are toxic to humans.

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Hydrogenation Reactions Catalyzed by PNP-Type Complexes Featuring a HN(CH2CH2PR2)2 Ligand

Ekanayake

Guan

2020

Topics in Organometallic Chemistry

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Multimetallic Complexes Based on a Diphosphine-Dithiocarbamate “Janus” Ligand

Abstract: The aminodiphosphine ligand, HN(CH 2 CH 2 PPh 2 ) 2 , reacts with [M(CO) 4

Cited by 17 publications

References 75 publications

Bifunctional Chalcogen Linkers for the Stepwise Generation of Multimetallic Assemblies and Functionalized Nanoparticles

Bifunctional Chalcogen Linkers for the Stepwise Generation of Multimetallic Assemblies and Functionalized Nanoparticles

Synthesis and Application of Ruthenium(II) Alkenyl Complexes with Perylene Fluorophores for the Detection of Toxic Vapours and Gases

Hydrogenation Reactions Catalyzed by PNP-Type Complexes Featuring a HN(CH2CH2PR2)2 Ligand

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