In this work the synthesis of anorthite-diopside glass-ceramics (GCs) was carried out via sintering and crystallization of glass powder compacts in the temperature interval 800°C and 950°C. Glass powder compacts with mean particle size of 2 μm were prepared. The effects of adding TiO 2 and P 2 O 5 on the sintering behavior of glass powder compacts and on the properties of resultant glassceramics were studied. Mechanical, thermal, chemical and dielectric properties of sintered GCs were investigated with the aim to evaluate the potential of the GCs as substrate materials for microelectronics applications.