Multifunctional microporous organic polymers

Li, Buyi; Guan, Zhenhong; Yang, Xinjia; Wang, Wei; Wang, Jiaqiang; Hussain, Irshad; Song, Kunpeng; Tan, Bien; Li, Tao

doi:10.1039/c4ta01081g

Cited by 161 publications

(120 citation statements)

References 70 publications

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“…Recently, a cost-effective approach was reported presenting a facile construction of conjugated structure which involves the elimination of two aryl-bound hydrogen atoms accompanied by the formation of a new aryl-aryl bond based on the Scholl reaction. [26] This general bottom-up approach abandoned the usage of crosslinker and directly linked a variety of rigid functionalized monomers without destroying the conjugated topology. However, this strategy prescribe a limit to the variety of the monomer that no functional groups can be existed on the aromatic rings.…”

Section: A C C E P T E D Accepted Manuscriptmentioning

confidence: 99%

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Knitting hypercrosslinked conjugated microporous polymers with external crosslinker

Tan

Yang

et al. 2015

Polymer

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Section: A C C E P T E D Accepted Manuscriptmentioning

confidence: 99%

“…This observed red-shift is likely due to the extended π-conjugated structure and the three-dimensional polymer skeleton of π-π stacked aryl rings. [26,37] Fluorescence excitation and emission spectra of HCCMPs were determined at solid state (Fig. 4a).…”

Section: A C C E P T E D Accepted Manuscriptmentioning

confidence: 99%

Knitting hypercrosslinked conjugated microporous polymers with external crosslinker

Tan

Yang

et al. 2015

Polymer

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“…Another is the Scholl coupling reaction with AlCl 3 as the catalyst. Our group and Tan et al had used this reaction for synthesis of POFs almost at the same time [59][60][61]. The coupling reaction could occur between the phenyl rings of aromatic compounds (Fig.…”

Section: Development Of New Reactionsmentioning

confidence: 93%

Principles for the Synthesis of Porous Organic Frameworks

Zhu

Ren

2014

SpringerBriefs in Molecular Science

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To date, hundreds of porous organic frameworks (POFs) have been successfully designed and synthesized. With regard to POFs, the first important problem is the constructing strategies of POFs. In this chapter, we introduce some principles for the synthesis of POF materials. Based on the type of POFs (crystalline or amorphous), the discussion of POFs is classified into two parts. For the synthesis of POF materials, two most vital factors should be followed. One is the monomers that are the fundamental constructing units for the synthesis of POFs, and the other is the polymerization reactions. The structure and property of POFs are determined by the utilization of monomers and polymerization reactions. In other words, the synergistic effect of two factors could influence the chemical and physical characteristics of the resulting samples.

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“…[48,49] Therefore it has been chosen as the functional building block for the synthesis of microporous organic polymer (MOP) in this work. The desired material, MOP-bipy was obtained with excellent yield by Sonogashira coupling reaction between 5,5'-diethynyl-2,2'-bi-pyridine and 1,3,5-tri(4-iodo phenyl) benzene.…”

Section: Resultsmentioning

confidence: 99%