Multifunctional Anti-Icing Gel Surface with Enhanced Durability

Abstract

Materials with low ice adhesion and long-lasting antiicing properties remain an ongoing challenge in ultralow temperature environments (≤−30 °C). This study presents a gel material consisting of a polymer matrix (copolymer of polyurethane and acrylamide) and an anti-icing agent, ethylene glycol (EG), designed for anti-icing applications at ultralow temperatures. The surface shows a prolonged droplet freezing delay of ca. 322 s at −30 °C and frost resistance properties. It also exhibits an ice adhesion strength of 1.1 kPa at −10 °C and 39.8 kPa at −50 °C, resulting from the interaction between EG and water molecules that hinders the crystallization of ice as well as the significant mismatch between elastic gel and ice. In addition, the gel surface exhibits favorable anti-icing durability, with an ice adhesion strength below 20.0 kPa after 25 icing/deicing cycles and mechanical scratch tests. The gel demonstrates remarkable thermal durability, achieved through the H-bonds between the EG and polymer matrix. The H-bonds further enhance the anti-icing performance, thereby remarkably decreasing EG depletion and improving anti-icing durability. Overall, these properties suggest the potential application of this gel material in harsh environments including polar regions.