Multifunctional amino-decorated metal–organic frameworks: nonlinear-optic, ferroelectric, fluorescence sensing and photocatalytic properties

Crystal structure of poly[diaquabis(μ2-biphenyl-2,4′-dicarboxylato-κ2 O:O′)tris(μ2-1,1′-biphenyl-4,4′-diylbis(1H-imidazole)-κ2 N:N′)dicobalt(II)] monohydrat, C82H64N12O11Co2

“…In the last two decades, Co(II)-based coordination polymers (Co-CPs) have drawn considerable attention because of their huge diversity and versatility structure and potential applications in the areas of magnetism, catalysis, adsorption/separation, nonlinear optics etc [1][2][3][4]. According to a survey of the previous references, bis(imidazole) ligands, as well-known N-donor ligands, have been widely utilized for tunability of structural frameworks [5,6].…”

Crystal structure of biphenyl-2,3′,5,5′-tetracarboxylic acid – 4,4′-biphenyl-4,4′-diyldipyridine (3/2), C49H34N3O8

“…The synthetic development of coordination polymers (CPs) continues to attract much attention because of their intriguing structural topologies and potential applications in gas storage, separation, sensing and heterogeneous catalysis [1][2][3][4][5][6][7][8]. In the construction of CPs, multidentate organic ligands play a vital role since the structural integrity of these ligands in most cases remains unaltered throughout the The mixed-ligands strategy incorporating N-donor colinkers with di erent lengths and rigidness/ exibility has been proved successful to create various CPs.…”

Fluorescence Detection of Anilines and Photocatalytic Degradation of Rhodamine B by a Multifunctional Metal–Organic Framework

“…[22] In this respect, MOFs have attracted much attention for their applications as a new kind of promising photocatalyst in purifying water by thoroughly decomposing organic dyes. [23][24][25][26][27][28] Thus, the appropriate choice of chemically modified organic ligands www.eurjic.org FULL PAPER and functional metal centers to construct multifunctional porous MOFs is highly necessary for the determination of toxic aromatic amines and degradation of organic dyes under visible-light irradiation. These unique properties of MOFs can be attributed to their tunable pore structures and functionalized pore surfaces [29] or the building blocks or molecular guests as well.…”