2020
DOI: 10.3144/expresspolymlett.2020.44
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Multifaceted bioinspired hyperbranched polyurethane nanocomposite as a non-contact triggered self-healing material

Abstract: The current investigation reports in situ fabrication of hyperbranched polyurethane (HPU) nanocomposites with different weight percentages of functionalized silica nanoparticle as nano-reinforcing material. Silica nanoparticles were functionalized with sodium dodecyl sulfate and polyethylene glycol using a facile, simple one-pot method. The nanomaterial and the HPU nanocomposites were assessed by Fourier Transform Infrared Spectroscopy (FTIR), Ultraviolet (UV)-visible, X-ray Diffraction (XRD), Transmission Ele… Show more

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Cited by 7 publications
(3 citation statements)
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References 36 publications
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“…[14]when f-SNP materials are uniformly dispersed in HPU, the polar functionality of f-SNP interact with HPU matrix resulting in stiffness and successful load transfer from HPU matrix to the nanomaterials in the composite leading to high toughness of the material. [20] By incorporation of sacrificial bond through polymerization with triple network of molecules in elastomers, elastomers are toughened and have high stretch ability. [32] Hardness: Surface hardness in the coatings is sought to provide a protective layer against mechanical damage.…”
Section: Mechanical Propertiesmentioning
confidence: 99%
“…[14]when f-SNP materials are uniformly dispersed in HPU, the polar functionality of f-SNP interact with HPU matrix resulting in stiffness and successful load transfer from HPU matrix to the nanomaterials in the composite leading to high toughness of the material. [20] By incorporation of sacrificial bond through polymerization with triple network of molecules in elastomers, elastomers are toughened and have high stretch ability. [32] Hardness: Surface hardness in the coatings is sought to provide a protective layer against mechanical damage.…”
Section: Mechanical Propertiesmentioning
confidence: 99%
“…ductility [4,5], impact resistance [6,7] or fire retardancy [8,9]), they can be endowed with additional functionalities that can increase their advantage over competing structural materials. The additional functions can range from self-healing [10,11] to integrated health monitoring [12,13], but the coupled behaviour of composites might be the most fundamental of all. Coupling refers to a direct connection between loads and deformations of different modes (e.g.…”
Section: Introductionmentioning
confidence: 99%
“…According to the healing mechanism, self-healing polymers are classified into autonomous and nonautonomous systems in which the damages are healed without and with the assistance of external stimuli, respectively. Such external stimuli as microwave irradiation, 10,11 UV-Visible irradiation, 12,13 heat, 14,15 magnetic field, 16 pH, 17 and addition of organic solvents 18 have been used for healing. These stimuli require energy consumption, addition of active chemical reagents and chemical modification of polymer chains.…”
Section: Introductionmentioning
confidence: 99%