Abstract:Structural chirality has been imposed onto nano‐alloys to introduce diverse new properties. Chiral nanoparticles (CNPs) with the atomic scale chirality are composed of metastable chiral lattices having low thermal stability, so multielementary (>2 elements) CNPs are very challenging to produce using traditional high‐energy fabrication methods. Herein, layer‐by‐layer glancing angle deposition (LbL‐GLAD) at a low substrate temperature of ≈−40 °C, consisting of GLAD of the host CNPs and the subsequent GLAD of … Show more
“…Such chiral twisting essentially imposes the chiroptical activity on the binary host. 18 More than two facets were involved in the chiral twisting, making the quantitative evaluation of the twisting angle difficult. The 1.5 h GRR porosifies the binary host (Fig.…”
Applying galvanic Replacement Reactions (GRR) to the host chiral nanoparticles (CNPs) is an exclusive method to generate alloy CNPs with mesoporous structures through chirality transfer. However, the GRR-mediated chirality transfer...
“…Such chiral twisting essentially imposes the chiroptical activity on the binary host. 18 More than two facets were involved in the chiral twisting, making the quantitative evaluation of the twisting angle difficult. The 1.5 h GRR porosifies the binary host (Fig.…”
Applying galvanic Replacement Reactions (GRR) to the host chiral nanoparticles (CNPs) is an exclusive method to generate alloy CNPs with mesoporous structures through chirality transfer. However, the GRR-mediated chirality transfer...
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