Multiclass Determination of Sunscreen Chemicals in Water Samples by Liquid Chromatography−Tandem Mass Spectrometry

Rodil, Rosario; Quintana, José Benito; López-Mahı́a, Purificación; Muniategui-Lorenzo, Soledad; Prada‐Rodríguez, D.

doi:10.1021/ac702240u

Cited by 197 publications

(107 citation statements)

References 32 publications

(72 reference statements)

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“…The research results published in the literature confirms that the benzophenones are generally rather efficiently removed from wastewater in biological processes [67,144], with e.g. removal efficiency of benzophenone-3 ranging from 28−30% to 68−96%.…”

Section: Sewage Analyte Referencessupporting

confidence: 58%

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Research trends on emerging environment pollutants – a review

Rykowska

Wasiak

2015

Open Chemistry

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Concern for the natural environment increasingly devotes more attention to growing potential hazards resulting from the release of various substances. Currently, one of the main problems associated with environmental pollution is the derivation of organic compounds from wastewater. Substances derived from sewage leaks into the environment in the form of a multicomponent mixtures often enhances the toxic effects caused by these compounds. While analyzing the reports in the literature of the last two decades it can be seen that substantial efforts are devoted to the determination of selected trace contaminants present in wastewater. Among the most marked there are endocrine disrupting compounds, residues of pharmaceuticals and personal care products, plastics and sunscreens. Recently, a new group of compounds joined the aforementioned contaminants, namely drugs, whose legality and availability is increasing every year. Exposure to these type of compounds, named in the literature as emerging contaminants (ECs), involves, among others, such effects as hormonal imbalance, reduction of the survivability of aquatic organisms and reproductive problems.This paper provides a review of the types of emerging organic groundwater contaminants (EGCs) which are beginning to be found in the natural environment in many countries all around the world.

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Section: Sewage Analyte Referencessupporting

confidence: 58%

“…removal efficiency of benzophenone-3 ranging from 28−30% to 68−96%. However, as typical wastewater treatment usually lacks biological treatment, overall efficiency of the reduction of the presence of these compounds in the wastewater is reduced [144].…”

Section: Sewage Analyte Referencesmentioning

confidence: 99%

Research trends on emerging environment pollutants – a review

Rykowska

Wasiak

2015

Open Chemistry

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“…When used, PCPs may be absorbed by the body and excreted or washed off after their application (Tolls and Berger, 2009). They and their metabolites end up in wastewater treatment plants (WWTPs) (Rodil et al, 2008), where are partially eliminated and retained in the sludge, but an important fraction of them may be released into the aquatic environment through the effluents (Molins-Delgado, 2015a). Even though pollutants are commonly present at low concentration levels, the concern about the adverse effects of a chronic exposure to them is rising.…”

Section: Introductionmentioning

confidence: 99%

Occurrence, fate and risk assessment of personal care products in river–groundwater interface

Serra-Roig

Jurado

Díaz-Cruz

et al. 2016

Science of The Total Environment

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This work presents the occurrence and fate of selected personal care products (PCPs) in the urban river-groundwater interface. To this end, urban river and groundwater samples were collected in Sant Adrià del Besòs (NE of Spain) and a total of 16 PCPs were analyzed including benzophenone derivatives, camphor derivatives, p-aminobenzoic acid derivatives, triazoles and parabens in three different campaigns (from May 2010 to July 2014). These compounds reach the aquifer through the recharge of Besòs River that receives large amounts of effluents from waste water treatment plants.Results shown that most of compounds were not or barely detected (maximum concentrations around 200 ng/L) in groundwater samples during the different sampling campaigns. Only two triazoles, namely benzotriazole (BZT) and methyl benzotriazol (MeBZT) were found at high concentrations in groundwater samples (maximum concentration around 2000 ng/L). The fate of PCPs in the aquifer was assessed using mixing analysis considering the seasonal variability of the Besòs River. Overall, measured groundwater concentrations were significantly much lower than those estimated by the mixing of the river water. This observation suggested that most of the PCPs are naturally removed when river water infiltrates the aquifer. However, some compounds were more persistent in the aquifer. These compounds were in descending order: the triazoles BZT and MeBZT followed by the camphor derivative 4MBC and the paraben MePB. The measured concentrations allowed us to assess the environmental risk posed by the selected UV-filters and parabens in the river and groundwater samples. Hazard Quotients (HQs) for different aquatic species were calculated in order to characterise the ecotoxicity potential of the studied compounds in the river-groundwater interface.HQ values were always below 1 indicating that at the concentrations observed in the surface or aquifer water of Besòs River these compounds pose no risk to the selected aquatic organisms.

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“…Cosmetic science is a practical science dedicated to producing safe and e ective cosmetic products and makes extensive use of mass spectrometry (MS) for the analysis of product ingredients 1) and biological samples 2) (typically skin specimens). e former o en involves quality control and stability testing in the product-development cycle, and the latter involves the study of skin biology and transdermal drug delivery.…”

Section: Introduction: Mass Spectrometry In Cosmetic Sciencementioning

confidence: 99%

Mass Spectrometry in Cosmetic Science: Advanced Ionization Techniques for Detecting Trace Molecules in or on Human Skin

Motoyama

Kihara

2017

Mass Spectrometry

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To provide safe and e ective products to customers in the cosmetic industry, mass spectrometry (MS) is an indispensable analytical tool. In addition to its outstanding sensitivity and speci city, the method is applicable to a wide variety of compounds, which makes it irreplaceable for the development of cosmetics, which requires the analysis of complex systems. Because most cosmetic products are applied directly to the skin and function as they are designed, monitoring the molecular compositions of endogenous or exogenous compounds in or on the skin is crucial to ensure the safety and e cacy of a cosmetic product. Recent advancements in MS and ionization techniques, such as MS imaging and ambient ionization, now provide access to richer and deeper molecular information with less time and e ort. is brief review discusses advanced ionization techniques that are currently used in the eld of cosmetic science using two examples, namely, the use of desorption electrospray ionization and zero-volt paperspray ionization to detect trace molecules in or on human skin.

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Multiclass Determination of Sunscreen Chemicals in Water Samples by Liquid Chromatography−Tandem Mass Spectrometry

Cited by 197 publications

References 32 publications

Research trends on emerging environment pollutants – a review

Research trends on emerging environment pollutants – a review

Occurrence, fate and risk assessment of personal care products in river–groundwater interface

Mass Spectrometry in Cosmetic Science: Advanced Ionization Techniques for Detecting Trace Molecules in or on Human Skin

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