This work presents results from large-eddy / Reynolds-averaged Navier-Stokes (LES/RANS) simulations of the well-known Burrows-Kurkov supersonic reacting wall-jet experiment. Generally good agreement with experimental mole fraction, stagnation temperature, and Pitot pressure profiles is obtained for non-reactive mixing of the hydrogen jet with a non-vitiated air stream. A lifted flame, stabilized between 10 and 22 cm downstream of the hydrogen jet, is formed for hydrogen injected into a vitiated air stream. Flame stabilization occurs closer to the hydrogen injection location when a threedimensional combustor geometry (with boundary layer development resolved on all walls) is considered. Volumetric expansion of the reactive shear layer is accompanied by the formation of large eddies which interact strongly with the reaction zone. Time averaged predictions of the reaction zone structure show an under-prediction of the peak water concentration and stagnation temperature, relative to experimental data and to results from a Reynolds-averaged Navier-Stokes calculation. If the experimental data can be considered as being accurate, this result indicates that the present LES/RANS method does not correctly capture the cascade of turbulence scales that should be resolvable on the present mesh. Instead, energy is concentrated in the very largest scales, which provide an overmixing effect that excessively cools and strains the flame. Predictions improve with the use of a low-dissipation version of the baseline piecewise parabolic advection scheme, which captures the formation of smaller-scale structures superimposed on larger structures of the order of the shear-layer width.ombustion processes occurring in high-speed propulsion devices can be strongly impacted by finite-rate chemistry and turbulence / chemistry interactions, as well as large-scale unsteady behavior caused by intermittent ignition events, shock / boundary layer interactions, and vortex dynamics. The state of the practice in high-speed engine component simulations [1] solves the Reynolds-Averaged Navier-Stokes (RANS) equations, expanded to include separate equations for species transport. Closure is usually accomplished through two-equation turbulence models in conjunction with Boussinesq and gradient-diffusion assumptions. Chemical reaction source terms are usually formulated using the law of mass action, and the effects of turbulence fluctuations on reaction rates are either completely ignored or modeled via eddy break up and/or assumed PDF methods. This standard model been used successfully in the design of scramjet-powered vehicles such as NASA's Hyper-X, the University of Queensland's HyShot program, and the U.S. Air Force's Scramjet Engine Demonstrator, but the ability of the model to handle highly transient physics of the types mentioned above is questionable at best. C Recent work [2][3][4][5] has focused on the development of a class of hybrid large-eddy simulation / Reynoldsaveraged Navier Stokes (LES/RANS) strategies specially designed for strongly-i...