This paper is concerned with the construction of algebraic-geometric (AG) codes defined from GGS curves. It is of significant use to describe bases for the Riemann-Roch spaces associated with some rational places, which enables us to study multi-point AG codes. Along this line, we characterize explicitly the Weierstrass semigroups and pure gaps by an exhaustive computation for the basis of Riemann-Roch spaces from GGS curves. In addition, we determine the floor of a certain type of divisor and investigate the properties of AG codes. Multi-point codes with excellent parameters are found, among which, a presented code with parameters [216,190,18] over F 64 yields a new record.