Abstract:A structural mechanism for the formation of nanoclusters and the rhombohedral modification of CuZr 1.86(1) S 4 has been proposed. Group-theoretical and crystal-chemical methods are used to study the features of the crystal structure and multi-order in Cu-Zr-thiospinel. A multi-order is a structural organization of a material, in the formation of which different degrees of freedom of a crystal participate. It has been proven that the rhombohedral structure of CuZr 1.86(1) S 4 is formed as a result of displaceme… Show more
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