Abstract:Context. Models of pure gas-phase chemistry in well-shielded regions of molecular clouds predict relatively high levels of molecular oxygen, O 2 , and water, H 2 O. These high abundances imply high cooling rates, leading to relatively short timescales for the evolution of gravitationally unstable dense cores, forming stars and planets. Contrary to expectations, the dedicated space missions SWAS and Odin typically found only very small amounts of water vapour and essentially no O 2 in the dense star-forming int… Show more
“…But owing to the high sensitivity of this survey, one could have hoped to detect some of those species already known elsewhere in the interstellar medium, in comets, or mysteriously absent such as the first two we discuss now. (Goldsmith et al 2000) and Odin (Pagani et al 2003) spacecrafts, counterbalanced by a single detection in ρ Ophiuchi (Larsson et al 2007) with Odin, we detected O 2 towards Orion (Goldsmith et al 2011) and confirmed the detection towards ρ Ophiuchi, (Liseau et al 2012). However, the location of the emission in Orion is ill-defined and that made the interpretation of the observations difficult (Goldsmith et al 2011;Chen et al 2014;Melnick & Kaufman 2015).…”
Section: Non-detection Of Species In Orionsupporting
Context. We wish to improve our understanding of the Orion central star formation region (Orion-KL) and disentangle its complexity. Aims. We collected data with ALMA during cycle 2 in 16 GHz of total bandwidth spread between 215.1 and 252.0 GHz with a typical sensitivity of 5 mJy/beam (2.3 mJy/beam from 233.4 to 234.4 GHz) and a typical beam size of 1 . 7 × 1 . 0 (average position angle of 89 • ). We produced a continuum map and studied the emission lines in nine remarkable infrared spots in the region including the hot core and the compact ridge, plus the recently discovered ethylene glycol peak. Methods. We present the data, and report the detection of several species not previously seen in Orion, including n-and i-propyl cyanide (C 3 H 7 CN), and the tentative detection of a number of other species including glycolaldehyde (CH 2 (OH)CHO). The first detections of gGg ethylene glycol (gGg (CH 2 OH) 2 ) and of acetic acid (CH 3 COOH) in Orion are presented in a companion paper. We also report the possible detection of several vibrationally excited states of cyanoacetylene (HC 3 N), and of its 13 C isotopologues. We were not able to detect the 16 O 18 O line predicted by our detection of O 2 with Herschel, due to blending with a nearby line of vibrationally excited ethyl cyanide. We do not confirm the tentative detection of hexatriynyl (C 6 H) and cyanohexatriyne (HC 7 N) reported previously, or of hydrogen peroxide (H 2 O 2 ) emission. Results. We report a complex velocity structure only partially revealed before. Components as extreme as −7 and +19 km s −1 are detected inside the hot region. Thanks to different opacities of various velocity components, in some cases we can position these components along the line of sight. We propose that the systematically redshifted and blueshifted wings of several species observed in the northern part of the region are linked to the explosion that occurred ∼500 yr ago. The compact ridge, noticeably farther south displays extremely narrow lines (∼1 km s −1 ) revealing a quiescent region that has not been affected by this explosion. This probably indicates that the compact ridge is either over 10 000 au in front of or behind the rest of the region. Conclusions. Many lines remain unidentified, and only a detailed modeling of all known species, including vibrational states of isotopologues combined with the detailed spatial analysis offered by ALMA enriched with zero-spacing data, will allow new species to be detected.
“…But owing to the high sensitivity of this survey, one could have hoped to detect some of those species already known elsewhere in the interstellar medium, in comets, or mysteriously absent such as the first two we discuss now. (Goldsmith et al 2000) and Odin (Pagani et al 2003) spacecrafts, counterbalanced by a single detection in ρ Ophiuchi (Larsson et al 2007) with Odin, we detected O 2 towards Orion (Goldsmith et al 2011) and confirmed the detection towards ρ Ophiuchi, (Liseau et al 2012). However, the location of the emission in Orion is ill-defined and that made the interpretation of the observations difficult (Goldsmith et al 2011;Chen et al 2014;Melnick & Kaufman 2015).…”
Section: Non-detection Of Species In Orionsupporting
Context. We wish to improve our understanding of the Orion central star formation region (Orion-KL) and disentangle its complexity. Aims. We collected data with ALMA during cycle 2 in 16 GHz of total bandwidth spread between 215.1 and 252.0 GHz with a typical sensitivity of 5 mJy/beam (2.3 mJy/beam from 233.4 to 234.4 GHz) and a typical beam size of 1 . 7 × 1 . 0 (average position angle of 89 • ). We produced a continuum map and studied the emission lines in nine remarkable infrared spots in the region including the hot core and the compact ridge, plus the recently discovered ethylene glycol peak. Methods. We present the data, and report the detection of several species not previously seen in Orion, including n-and i-propyl cyanide (C 3 H 7 CN), and the tentative detection of a number of other species including glycolaldehyde (CH 2 (OH)CHO). The first detections of gGg ethylene glycol (gGg (CH 2 OH) 2 ) and of acetic acid (CH 3 COOH) in Orion are presented in a companion paper. We also report the possible detection of several vibrationally excited states of cyanoacetylene (HC 3 N), and of its 13 C isotopologues. We were not able to detect the 16 O 18 O line predicted by our detection of O 2 with Herschel, due to blending with a nearby line of vibrationally excited ethyl cyanide. We do not confirm the tentative detection of hexatriynyl (C 6 H) and cyanohexatriyne (HC 7 N) reported previously, or of hydrogen peroxide (H 2 O 2 ) emission. Results. We report a complex velocity structure only partially revealed before. Components as extreme as −7 and +19 km s −1 are detected inside the hot region. Thanks to different opacities of various velocity components, in some cases we can position these components along the line of sight. We propose that the systematically redshifted and blueshifted wings of several species observed in the northern part of the region are linked to the explosion that occurred ∼500 yr ago. The compact ridge, noticeably farther south displays extremely narrow lines (∼1 km s −1 ) revealing a quiescent region that has not been affected by this explosion. This probably indicates that the compact ridge is either over 10 000 au in front of or behind the rest of the region. Conclusions. Many lines remain unidentified, and only a detailed modeling of all known species, including vibrational states of isotopologues combined with the detailed spatial analysis offered by ALMA enriched with zero-spacing data, will allow new species to be detected.
“…The success story of combined laboratory and observational studies became complete with the detection of gas-phase HO 2 199 Interestingly, ρ Oph A is also one of only two positions where interstellar O 2 gas has been firmly detected through multi-line observations with the Odin and Herschel satellites 202,203 . Deep limits in other cold cores confirm the scenario in which most of the O and O 2 must be converted into H 2 O ice on the grains before the protostar starts to heat its surroundings 204,205 .…”
Section: H 2 O O 2 and The Importance Of Solid-state Chemistrymentioning
A brief introduction and overview of the astrochemistry of dust, ice and gas
and their interplay is presented, aimed at non-specialists. The importance of
basic chemical physics studies of critical reactions is illustrated through a
number of recent examples. Such studies have also triggered new insight into
chemistry, illustrating how astronomy and chemistry can enhance each other.
Much of the chemistry in star- and planet-forming regions is now thought to be
driven by gas-grain chemistry rather than pure gas-phase chemistry, and a
critical discussion of the state of such models is given. Recent developments
in studies of diffuse clouds and PDRs, cold dense clouds, hot cores,
protoplanetary disks and exoplanetary atmospheres are summarized, both for
simple and more complex molecules, with links to papers presented in this
volume. In spite of many lingering uncertainties, the future of astrochemistry
is bright: new observational facilities promise major advances in our
understanding of the journey of gas, ice and dust from clouds to planets.Comment: Introductory paper for Faraday Discussions 168 conference, April 201
“…Goldsmith et al 2000;Pagani et al 2003), with the definite detection of the molecule in merely two sources, viz. ρ Oph A (Larsson et al 2007;Liseau et al 2012) and Orion A (Goldsmith et al 2011;Chen et al 2014). Some cases have been either resolved or remained undecided (e.g.…”
Section: Introductionmentioning
confidence: 99%
“…Chen et al (2014) were able to pinpoint the location of the 9 O 2 source, near the position identified as H 2 -Peak 1 and somewhat offset from the hot core centre. The non-detection of the O 2 line at 1121 GHz led the authors to conclude that gas temperatures do not exceed 50 K, with best-fit model values more like 30 K. The excitation conditions thus resemble those in ρ Oph A (Liseau et al 2012). Du et al (2012) developed models for grain surface chemistry, and as an example, they considered the particular case of ρ Oph A.…”
Context. The abundance of key molecules determines the level of cooling that is necessary for the formation of stars and planetary systems. In this context, one needs to understand the details of the time dependent oxygen chemistry, leading to the formation of O 2 and H 2 O. Aims. We aim to determine the degree of correlation between the occurrence of O 2 and HOOH (hydrogen peroxide) in star-forming molecular clouds. We first detected O 2 and HOOH in ρ Oph A, we now search for HOOH in Orion OMC A, where O 2 has also been detected. Methods. We mapped a 3 × 3 region around Orion H 2 -Peak 1 with the Atacama Pathfinder Experiment (APEX). In addition to several maps in two transitions of HOOH, viz. 219.17 GHz and 251.91 GHz, we obtained single-point spectra for another three transitions towards the position of maximum emission. Results. Line emission at the appropriate LSR-velocity (Local Standard of Rest) and at the level of ≥4σ was found for two transitions, with lower signal-to-noise ratio (2.8−3.5σ) for another two transitions, whereas for the remaining transition, only an upper limit was obtained. The emitting region, offset 18 south of H 2 -Peak 1, appeared point-like in our observations with APEX. Conclusions. The extremely high spectral line density in Orion makes the identification of HOOH much more difficult than in ρ Oph A. As a result of having to consider the possible contamination by other molecules, we left the current detection status undecided.
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