Multi-heteroatom doped porous carbon derived from insect feces for capacitance-enhanced sodium-ion storage

Chen, Chen; Huang, Ying; Meng, Zhuoyue; Xu, Zhipeng; Liu, Panbo; Li, Tiehu

doi:10.1016/j.jechem.2020.06.025

Cited by 95 publications

(49 citation statements)

References 50 publications

(54 reference statements)

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“…Lithium ion batteries (LIBs) have been widely used as power sources in mobile electronic equipment and large energy storage systems [1][2][3][4][5]. However, the electrolytes used in current LIBs are mainly combustible organic compounds, so there are serious safety risks.…”

Section: Introductionmentioning

confidence: 99%

“…(2) The periodic crystal structure with high porosity provides uniformly dispersed sites and a definite channel for ion diffusion, which is unmatched by some conventional materials. (3) The rich pore structure can improve the uniformity of cation deposition during charge and discharge, which will promote the stability of the interface and improve the cycle performance. In addition, MOF materials can also act as ion sieves to promote the transfer of cations.…”

Section: Introductionmentioning

confidence: 99%

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MOF-derived multifunctional filler reinforced polymer electrolyte for solid-state lithium batteries

Zhang

Gao

et al. 2021

Journal of Energy Chemistry

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

MOF-derived multifunctional filler reinforced polymer electrolyte for solid-state lithium batteries

Zhang

Gao

et al. 2021

Journal of Energy Chemistry

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“…Meanwhile, it could also reduce the volume change of the electrode during cycling, thereby obtaining high rate performance and long‐term cycling stability. [ 57 ] On this basis, Fourier transform infrared (FT‐IR) spectroscopy was conducted, and it was found that the noncarbonized bagasse contained more oxygen‐containing functional groups, such as COH, OCO, CO, and OCO (Figure 1f). The stretching vibration of these groups corresponding to the HC material obtained after carbonization is obviously weakened, and the oxygen‐containing functional groups are significantly reduced.…”

Section: Resultsmentioning

confidence: 99%

A Stable Biomass‐Derived Hard Carbon Anode for High‐Performance Sodium‐Ion Full Battery

Xiao

Ling

et al. 2020

Energy Tech

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As the environmental and energy crisis aggravated, it is urgent to develop a clean and recyclable energy storage system. [1-5] In recent years, sodium-ion batteries (SIBs) have become a research hotspot in energy field because of its rich sodium content and low cost. [6-9] Designing low cost and advanced electrode materials are the key to drive their future commercialization. [10-14] Presently, a large variety of cathode materials have been proposed, such as transition metal oxides, polyanionic-type compounds, Prussian blue analogues, and organic-based materials. [15-22] In the case of anode materials, the research also presents the rapid development trend. Carbon-based material, alloys, transition metal oxides/sulfides and organic compounds have been widely studied as promising anodes for SIBs. [23-28] Among these materials, alloys, transition metal oxides/ sulfides, and organic compounds suffered from large volume expansion and poor electrochemical kinetics. As a contrast, biomass-derived hard carbon (HC), one of the most suitable materials for practical application, has attracted more and more attentions as a kind of resource abundant, high conductivity, low cost, and environmentally friendly material. [29-32] Recently, researchers synthesized HC materials derived from biomasses and explored their applications in energy storage. HC products have been synthesized from a variety of carbon sources, such as cellulose, peat moss, peanut shells, banana peels, renewable cotton, and poplar wood. [33-38] Compared with other crop straws, bagasse is the major waste of the sugar industry that contained more lignification, cellulose and hemicellulose, less protein, starch and soluble sugar, and lower pesticide residues. [39] Meanwhile, it is a carbon-rich biomass that can be used to prepare functional carbonaceous nanomaterials by thermal decomposition, turning waste into valuable materials. [40,41] However, in the previously reported work, the poor cycling stability of HC anode material is still a big

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“…Though alloy‐type anode materials, which can form Na x M y alloy (M = Sn, 11 Sb, 12 Ge 13 et al) with sodium ion, have been studied to apply as sodium ion battery anode lately because of their high theoretical capacity, we still have many challenges to make full usage of SIBs in large grid energy storage application. Various carbon anodes, 14 such as hard carbon, 15‐17 porous carbon, 18‐20 hollow carbon sphere, 21 and carbon nanosheet 22‐26 have also been prepared to apply as anode for SIBs. For example, Stevens and Dahn 17 compared the electrochemical insertion of both sodium and lithium into hard carbon, and found this material displays voltage characteristics for sodium insertion quite similar to that for lithium insertion.…”

Section: Introductionmentioning

confidence: 99%

“…Their studies show that the electrochemical properties of hard carbon are affected by the treatment temperatures, which determines the materials morphology, in particular, their degree of graphitization and extent of continuous channels 16 . Chen et al 18 successfully prepared a multi‐heteroatom doped hierarchically porous carbon via an easy annealing process using silkworm excrement as precursor. A high reversible capacity of 331.7 mAh g −1 was obtained at a current density of 20 mA g −1 .…”

Section: Introductionmentioning

confidence: 99%

N, S self‐doped porous carbon with enlarged interlayer distance as anode for high performance sodium ion batteries

Zhang

Feng

et al. 2020

Int J Energy Res

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Summary To enhance the cycling ability and rate property of carbon anode material for sodium ion battery, an easy, green, and scalable thermal pyrolysis method had been exploited to synthesize the nitrogen, sulfur self‐doped porous carbon anode derived from the walnut shell. The microstructure and electrochemical properties of this synthesized porous carbon materials are investigated by tuning the thermal pyrolysis temperature. When it is at 1000 °C, the porous carbon material exhibits the largest average interlayer distance of about 0.408 nm (d002) and excellent electrochemical performance. The porous carbon electrode material carbonized at 1000°C for sodium ion battery manifests a high reversible specific capacity of about 305 mAh g−1 at a current density of 100 mA g−1 after 200 cycles, and as large as 182 mAh g−1 at 1 A g−1 after 1500 charge/discharge cycles. Nitrogen and sulfur doped biomass carbon anode material with an excellent storage capacity for sodium ion, makes it an appealing candidate as cheap and high‐performance anode materials for sodium ion batteries.

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Multi-heteroatom doped porous carbon derived from insect feces for capacitance-enhanced sodium-ion storage

Cited by 95 publications

References 50 publications

MOF-derived multifunctional filler reinforced polymer electrolyte for solid-state lithium batteries

MOF-derived multifunctional filler reinforced polymer electrolyte for solid-state lithium batteries

A Stable Biomass‐Derived Hard Carbon Anode for High‐Performance Sodium‐Ion Full Battery

N, S self‐doped porous carbon with enlarged interlayer distance as anode for high performance sodium ion batteries

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