The sorption thermal battery (STB) is a promising thermal
energy
storage technology for long-term heating applications. Recent research
has focused on the use of an ammonia-based STB for cold regions, while
a three-phase water-based STB offers a remarkably high energy storage
density (ESD) through crystallization sorption. However, the three-phase
STB faces limitations in terms of lower evaporator temperatures due
to water freezing. To address this issue, a cascade three-phase STB
(CSTB) is proposed, which consists of two sorption subsystems. The
ammonia sorption subsystem upgrades the low ambient temperature and
is used to boost the discharging pressure of the three-phase sorption
subsystem, resulting in a high-temperature lift and a large concentration
glide. A comprehensive thermodynamic evaluation is carried out when
different working pairs are considered. The results show that the
proposed CSTB attains the highest ESD (1456 kJ·kg–1) and discharging temperature (105 °C) with CaCl2–NH3/LiCl–H2O and a better coefficient
of performance (COPh; 0.51) with LiCl–H2O/BaCl2–NH3. The ESD of the proposed
STB exceeds that of the double-stage STB (663 kJ·kg–1) by more than 1.7 times, while the conventional STB cannot operate
with ambient, discharging, and charging temperatures of −10,
55, and 90 °C, respectively. The overall performance makes the
proposed CSTB promising for domestic heating and heat transformer
applications even in severe cold regions.