Mössbauer-effect and infrared-absorption study of the radiolysis products of potassium trisoxalatoferrate(III)

Temperley, A.A.; Pumplin, D.W.

doi:10.1016/0022-1902(69)80185-5

Cited by 19 publications

(2 citation statements)

References 14 publications

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“…Upon irradiation, the immediate formation of two absorbances centered at 2345 and 663 cm-1 were observed and correspond to the formation of C02. 26 The concentration of C02 increased (20) Suzuki, S.; Matsumoto, K.; Harada, K.; Tsubura, E. Photog. Sci.…”

Section: Resultsmentioning

confidence: 99%

Photoselective catalysis of electroless copper solutions for the formation of adherent copper films onto polyimide

Baum¹,

Miller²,

O’Toole³

1991

Chem. Mater.

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Section: Resultsmentioning

confidence: 99%

Photoselective catalysis of electroless copper solutions for the formation of adherent copper films onto polyimide

Baum¹,

Miller²,

O’Toole³

1991

Chem. Mater.

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“…Although these studies generally show a reduction of iron(III) into iron(II), the nature of the iron(II) species has been reported to be dependent on both alkali nature (M) and hydration number (x) of the initial ferric complex. For heavy alkali (M=K,Cs), the ferrous products have been identified as a double oxalate of iron and the corresponding alkali, M 2 Fe(C 2 O 4 ) 2Iy H 2 O, with an hydration number y depending on the water content of the initial ferric compound [1][2][3][4] and, in some cases, on the irradiation conditions [5,6]. However, as already shown in a previous study [7] on Li 4 Fe(C 2 O 4 ) 3 .Cl.9H 2 O, for light alkali, the only ferrous radiolytic product was found to be FeC 2 O 4 .2H 2 O.…”

Section: Introductionmentioning

confidence: 99%

Mössbauer study on the gamma radiolysis of lithium trisoxalatoferrate (III) pentahydrate

Ladrière

Senterre

2006

Hyperfine Interact

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The final iron product of the 60-Co gamma radiolysis of lithium trisoxalatoferrate(III) pentahydrate has been identified by Mö ssbauer spectroscopy as FeC 2 O 4. 2H 2 O. Quantitative chemical and Mö ssbauer analyses show that the radiolytic decomposition proceeds as a first order reaction as a function of the absorbed dose. Chemical calibration of the relative peaks areas of the two iron species indicates that the corresponding Lamb-Mö ssbauer factors ratio is unaffected by the radiolysis.

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Mössbauer Study of Some Gamma‐ and Neutron‐Irradiated Iron Carbonyl Complexes

Cheng

Yeh

Cheng³

1971

J Chinese Chemical Soc

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Mössbauer effect experiments have been carried out on 60Co and reactor irradiated CFe(CO)3SCH1]2, [(C4H9)2SnFe(CO)4]3, (C6H5)1PFe(CO)4, (CH2)4[Fe(CO)2C3H5]2, and (CH2)4.(CO)2[Fe(CO)2C5H5]2. It was found that the Fe—CO bond is rather radiation resistant than are expected due to the π bonding character. The σ bonds such as C—H are labile to radiation. The presence of acyl carbonyl group increase the radiation resistant property of the molecule. The increase in the isomer shift values of the complexes with cyclopentadienyl groups were interpreted as a result of dehydrogenation.

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Mössbauer-effect and infrared-absorption study of the radiolysis products of potassium trisoxalatoferrate(III)

Cited by 19 publications

References 14 publications

Photoselective catalysis of electroless copper solutions for the formation of adherent copper films onto polyimide

Photoselective catalysis of electroless copper solutions for the formation of adherent copper films onto polyimide

Mössbauer study on the gamma radiolysis of lithium trisoxalatoferrate (III) pentahydrate

Mössbauer Study of Some Gamma‐ and Neutron‐Irradiated Iron Carbonyl Complexes

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