MoSe₂ Quantum Dots Enhance the Performance of ZnO Nanostructure-Based UV Photodetectors

Abstract

Zinc oxide (ZnO) nanostructures are extensively used as active materials for ultraviolet (UV) photodetectors, but the high dark current arising from intrinsic defects limits their performance. An emerging strategy to alleviate such problems includes the formation of heterostructures with transition metal dichalcogenides (TMDs), which until today have been limited to their two-dimensional structures, leaving the superior physicochemical properties in their quantum dot (QD) configuration untapped. Here, we devise a strategy to reduce surface defects by decorating ZnO nanorods with MoSe2 QDs fabricated through pulsed-laser ablation, using a facile spin-coating method. Through various surface and optical characterizations, we confirm the formation of heterostructures, wherein MoSe2 reduces the number of vacancy defects in the ZnO. As a result, when used as a UV photodetector, the heterostructures exhibit a simultaneous 51% decrease in dark current and 79% increase in photocurrent, i.e., a 4-fold sensitivity compared to the pure ZnO counterpart. Our study presents a strategy to enhance UV photodetector efficiency by utilizing metal oxide/quantum dot heterostructures produced through a facile method. In a broader context, it underscores the efficacy of quantum dot-based heterostructures in optimizing optoelectronic devices.

Self-Powered Quasi-Solid-State Photoelectrochemical Photodetectors Based on MXene Paper Modified by ZnO Nanostructured Architecture

“…The interest in the detection of ultraviolet (UV) radiation has increased in various application areas . In this concern, zinc oxide (ZnO) with a wide direct band gap (∼3.37 eV) value is highly attractive, especially in photocatalysis, photovoltaics, and UV detection systems. − The reason for the great interest in ZnO is associated with its numerous remarkable features such as high carrier mobility (200 cm 2 V –1 ), large exciton binding energy (60 MeV), nontoxic nature, thermal stability, and ease of manufacturing methods . ZnO nanostructures are easily synthesized in diverse morphologies including nanorods (NRs), , nanowires (NWs), nanosheets (NSs), , and nanoflowers (NFs). , One-dimensional (1D) ZnO NRs are especially desirable in UV-photodetector (UV-PD) applications due to their larger surface area, which can contribute to light absorption. ,− …”