We report on the effects of thermal annealing on the electrical properties of tetraethylorthosilicate (TEOS)-deposited ultra-thin nitrided oxide using nitric oxide. Ultra-thin oxynitride films have been deposited on strained Si 0.82 Ge 0.18 layers at a low temperature by microwave plasma-enhanced chemical vapour deposition. The interface trap charge density (D it ), fixed oxide charge density (Q f /q), flatband voltage (V FB ) and border trap charge (Q bt ) are found to decrease with annealing up to a temperature of 800 • C. Under Fowler-Nordheim (F-N) constant current stressing, the oxynitride films show an improvement in the charge trapping behaviour after annealing. The reliability characteristics have been studied using charge-to-breakdown (Q BD ) measurements.