Lateral epitaxial growth of
normalGaAs
over tungsten gratings with 5 μm wide lines and spaces on (001)
normalGaAs
substrates is performed using metalorganic chemical vapor deposition. A study is made of the dependence of facet shapes and growth rates of the overgrown layers on grating direction, growth temperature, and arsine
false(AsH3false)
and trimethylgallium (TMG) flow rates. From the perspective of crystallography, all the facets observed in the overgrown layers were found to be classified into four individual groups: {110}, {}As, {1̅12}As, and {113}Ga faces. The
normalGaAs
opening direction on the (001) substrate surface is found to be the most essential parameter for determining the crystallographic planes of the facets. Other important controlling parameters for the facet formation are the growth temperature and partial pressure of
AsH3
. The partial pressure of TMG has no influence on the faceting growth. On the other hand, the overall growth rate of the overgrown layer is limited only by the TMG flow rate. These results can be qualitatively explained by the Langmuir‐Rideal model.